71156-14-4

Basic information

• Product Name: Benzene, 1-nitro-3-(trinitromethyl)-
• CAS NO: 71156-14-4
• Molecular Formula: C7H4N4O8
• Molecular Weight: 272.131
• Mol File: 71156-14-4.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: Benzene, 1-nitro-3-(trinitromethyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-nitro-3-(trinitromethyl)-(71156-14-4)
• EPA Substance Registry System: Benzene, 1-nitro-3-(trinitromethyl)-(71156-14-4)

Safety Data

• Hazardous Substances Data: 71156-14-4(Hazardous Substances Data)

Upstream product

• 20143-63-9 trinitromethanide 
• 98-95-3 nitrobenzene 
• 67483-29-8 phenyltrinitromethane 
• 3431-62-7 3-nitrobenzaldoxime 
• 28198-69-8 C₇H₄N₃O₆^(1-)*K⁽¹⁺⁾ 
• 611-38-1 dinitromethyl-benzene 
• 7007-35-4 m-nitrobenzonitrile oxide 

Downstream Products

• 7304-92-9 m-nitrophenyldinitromethane 
• 71081-27-1 N,N-Dimethyl-N'-[1-nitro-1-(3-nitro-phenyl)-meth-(E)-ylidene]-hydrazine 

Relevant articles and documents

New methods of preparation of nitrile oxides and the corresponding disubstituted furoxans by interaction of N2O4 with salts of substituted dinitromethanes

A new method of generation of nitrile oxides through interaction of N2O4 with salts of substituted dinitromethanes (1) has been worked out.It has been shown by 1H, 13C, 14N NMR spectroscopy that this reaction proceeds via dinitrosomethyl intermediates (on

REACTIONS OF NITRILE OXIDES WITH NITROGEN OXIDES. 1. REACTIONS WITH NITROGEN TETROXIDE

We have studied the reaction of nitrile oxides with nitrogen tetroxide.It was shown that the reaction is selective: acetonitrile oxide yields ethylnitrolic acid, α-oximinophenylacetonitrile oxide gives a mixture of isomers of phenylnitrofuroxan, and aromatic nitrile oxides give aryltrinitromethanes.

Synthesis and Properties of Dinitromethylated Arenes. Reinvestigation of the Ponzio Reaction

Several title compounds have been prepared by the modified Ponzio procedure and their IR, 1 H and 13 C NMR data are presented.In some cases trinitromethylated arenes were obtained as a by-product.Oxidative cleavage to parent aldehydes and oxidation to carboxylic acids were the major competing reactions. 9-Anthracenecarbaldehyde oxime and 10-methyl-9-anthracenecarbaldehyde oxime reacted with nitrogen dioxide in an unexpected way, giving 10-nitro-9-anthracenecarbonitrile oxide and 10-methyl-10-nitro-9-anthrone as the respective main products.Nitration of (dinitromethyl)benzene has also been examined under various conditions.