7133-39-3

Basic information

• Product Name: Cyclohexylisopropyl sulfide
• Synonyms: Cyclohexylisopropyl sulfide
• CAS NO: 7133-39-3
• Molecular Formula: C₉H₁₈S
• Molecular Weight: 158.3
• Mol File: 7133-39-3.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Cyclohexylisopropyl sulfide(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexylisopropyl sulfide(7133-39-3)
• EPA Substance Registry System: Cyclohexylisopropyl sulfide(7133-39-3)

Safety Data

• Hazardous Substances Data: 7133-39-3(Hazardous Substances Data)

Upstream product

• 14198-71-1 4,7-dihydro-2,2-dimethyl-1,3-dithiepin 
• 108-85-0 1-bromocyclohexane 
• 75-33-2 2-propanethiol 
• 1569-69-3 Cyclohexanethiol 
• 75-26-3 isopropyl bromide 

Relevant articles and documents

Sulfonium ylide formation and subsequent C[sbnd]S bond cleavage of aromatic isopropyl sulfide catalyzed by hemin in aqueous solvent

Heme is an abundant and widely existed cofactor for a variety of metalloenzymes, whose broader use is generally impeded by its high instability and poor solubility. Here we report an environment-benign and efficient strategy for the sulfonium ylide formation and subsequent C[sbnd]S bond cleavage of aromatic isopropyl sulfides, which was catalyzed by hemin in assistance of Triton X-100. This aqueous catalytic system exhibited good functional group tolerance to a variety of sulfides and diazo esters. And the reaction mechanism was preliminarily proposed on the basis of designed reactions. Furthermore, the cleavage of C[sbnd]S bond followed by introducing a functional ester group to aromatic sulfides, may potentially be employed for the late stage functionalization (LSF) of organosulfur drug in the future.