71360-11-7Relevant articles and documents
Competition between insertion and conjugate addition in nickel-catalyzed couplings of enones with unsaturated functional groups
Montgomery, John,Seo, Jeongbeob,Chui, Helen M.P.
, p. 6839 - 6842 (2007/10/03)
The intra- and intermolecular couplings of enones with alkynes or enones in the presence of organozincs under Ni(COD)2 catalysis resulted in three general reaction pathways: direct conjugate addition, cyclization with alkylation, and cyclization with reduction. The effects of substrate structural variations on selectivities among these three pathways were investigated.