7154-71-4Relevant articles and documents
In situ IRRAS studies of molecular recognition of barbituric acid lipids to melamine at the air-water interface
Kong, Xianming,Du, Xuezhong
, p. 13191 - 13198 (2011)
Recognition and detection of melamine are of very significance in food industries. Molecular recognitions of barbituric acid lipids to melamine at the air-water interface have been investigated in detail using in situ infrared reflection absorption spectroscopy (IRRAS). Hydrogen bonding patterns and molecular orientations of the molecular recognitions have been revealed. Prior to molecular recognition, the barbituric acid moieties in the monolayers were hydrogen bonded with a flat-on fashion at the air-water interface, and the alkyl chains were preferentially oriented with their CCC planes perpendicular to the water surface. After molecular recognition, the NH2 stretching bands of recognized melamine were clearly observed at the air-water interface as well as primary characteristic bands, the barbituric acid moieties underwent a change in orientation with non-hydrogen bonded C4=O bonds almost perpendicular to the water surface and C2=O and C6=O bonds involved in hydrogen bonds with melamine, and the alkyl chains were preferentially oriented with their CCC planes parallel to the water surface. The monolayers of barbituric acid lipids exhibited excellent selectivity for melamine over nucleosides.
NOVEL XYLENE-BASED AMPHIPHILIC COMPOUND AND USE THEREOF
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Paragraph 0178; 0179; 0216; 0236; 0261, (2018/10/19)
The present invention relates to a xylene-based amphiphilic compound, a method for preparing the same, and a method for extracting, solubilizing, stabilizing or crystallizing a membrane protein using the same. By using the xylene-based compound according to the present invention, a membrane protein may be stably stored in an aqueous solution for a long time, and may be applied in functional and structural analyses. The structural and functional analysis of the membrane protein is one of the fields of highest interest in biology and chemistry, and the xylene-based compound according to the present invention can be applied in research on protein structure that is closely related to development of a new drug.
Design and synthesis of sodium ion-selective ionophores based on 16-crown-5 derivatives for an ion-selective electrode
Suzuki, Koji,Sato, Kazunari,Hisamoto, Hideaki,Siswanta, Dwi,Hayashi, Kazuo,Kasahara, Noriko,Watanabe, Kazuhiko,Yamamoto, Noriko,Sasakura, Hideshi
, p. 208 - 215 (2007/10/03)
To develop an ionophore that is highly selective for sodium for use in an ion-selective electrode, we propose a model based on 16-crown-5 which has a cavity just the size of Na+ and has a "block" subunit to prevent complex formation with ions l