717127-50-9

Basic information

• Product Name: N-benzyl-N-allylamino-L-alanine methyl ester
• Synonyms: N-benzyl-N-allylamino-L-alanine methyl ester
• CAS NO: 717127-50-9
• Molecular Weight: 233.31
• Mol File: 717127-50-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: N-benzyl-N-allylamino-L-alanine methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: N-benzyl-N-allylamino-L-alanine methyl ester(717127-50-9)
• EPA Substance Registry System: N-benzyl-N-allylamino-L-alanine methyl ester(717127-50-9)

Safety Data

• Hazardous Substances Data: 717127-50-9(Hazardous Substances Data)

Upstream product

• 100-39-0 benzyl bromide 
• 73270-63-0 N-Allylalanine methyl ester 
• 31022-10-3 N-benzyl-L-alanine methyl ester 
• 106-95-6 allyl bromide 

Downstream Products

• 1000414-75-4 (2S)-1-benzyl-2-methyl-1,6-dihydropyridin-3(2H)-one 
• 148759-63-1 (S)-(+)-2-Allyl(benzyl)amino-1-propanol 

Relevant articles and documents

Azabicyclo[3.1.0]hexane-1-ols as frameworks for the asymmetric synthesis of biologically active compounds

Azabicyclo[3.1.0]hexane-1-ols, easily obtained by Ti(IV)-mediated cyclopropanation of amino acid derivatives, constitute versatile, and unprecedented intermediates for the asymmetric synthesis of pharmacologically active products. Indeed, through selective rearrangement, these compounds undergo unusual ring cleavage to lead to pyrrolidinones. Fe(III)-promoted ring opening followed by basic dehydrohalogenation furnishes optically active dihydropyridinones, while Ce(IV)-promoted ring opening provides chiral tricyclopiperidinones via a radical process.