71787-52-5

Basic information

• Product Name: Benzenemethanol, 3-nitro-a-2-propenyl-
• CAS NO: 71787-52-5
• Molecular Formula: C10H11NO3
• Molecular Weight: 193.202
• Mol File: 71787-52-5.mol
• Article Data: 37

Chemical Properties

• CAS DataBase Reference: Benzenemethanol, 3-nitro-a-2-propenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenemethanol, 3-nitro-a-2-propenyl-(71787-52-5)
• EPA Substance Registry System: Benzenemethanol, 3-nitro-a-2-propenyl-(71787-52-5)

Safety Data

• Hazardous Substances Data: 71787-52-5(Hazardous Substances Data)

Upstream product

• 99-61-6 3-nitro-benzaldehyde 
• 762-72-1 allyl-trimethyl-silane 
• 106-95-6 allyl bromide 
• 24850-33-7 allyltributylstanane 
• 29949-19-7 1,1-diacetoxy-1-(3-nitrophenyl)methane 
• 1200328-33-1 1-nitro-3-[1-[(trimethylsilyl)oxy]-3-buten-1-yl]benzene 
• 591-87-7 Allyl acetate 
• 1730-25-2 allylmagnesium bromide 
• 107-05-1 3-chloroprop-1-ene 
• 2551-83-9 allyltrimethoxysilane 
• 2550-04-1 allyltriethoxysilane 
• 7393-43-3 tetraallyl tin 

Downstream Products

• 1023294-91-8 1-(3-nitrophenyl)but-3-en-1-one 
• 1160487-98-8 O-(1-(3-nitrophenyl)but-3-enyl)hydroxylamine 
• 129277-18-5 4-hydroxy-4-(3-nitrophenyl)-butan-2-one 
• 946-68-9 (E)-4-(3-nitrophenyl)but-3-en-2-one 
• 1620206-36-1 (E)-N-(1-bromo-4-(3-nitrophenyl)but-3-en-2-yl)-2,2,2-trichloroacetamide 
• 1620206-53-2 (E)-4-(3-nitrostyryl)-2-(trichloromethyl)-4,5-dihydro-oxazole 
• 1620206-18-9 C₁₂H₁₁Cl₃N₂O₃ 

Relevant articles and documents

Copper-catalyzed radical oxyallylation of olefins for the construction of alkene-containing isoxazolines

A radical-mediated approach to alkene oxyallylation using allylic oximes is described. The reaction proceeds under copper-catalytic redox-neutral conditions and tolerates various functional groups. This protocol thus enables the synthesis of structurally valuable isoxazolines and the introduction of a versatile olefin motif in a single step.

MnO2as a terminal oxidant in Wacker oxidation of homoallyl alcohols and terminal olefins

Efficient and mild reaction conditions for Wacker-type oxidation of terminal olefins of less explored homoallyl alcohols to β-hydroxy-methyl ketones have been developed by using a Pd(ii) catalyst and MnO2 as a co-oxidant. The method involves mild reaction conditions and shows good functional group compatibility along with high regio- and chemoselectivity. While our earlier system of PdCl2/CrO3/HCl produced α,β-unsaturated ketones from homoallyl alcohols, the present method provided orthogonally the β-hydroxy-methyl ketones. No overoxidation or elimination of benzylic and/or β-hydroxy groups was observed. The method could be extended to the oxidation of simple terminal olefins as well, to methyl ketones, displaying its versatility. An application to the regioselective synthesis of gingerol is demonstrated.

Cationic Cobalt Porphyrin-Catalyzed Allylation of Aldehydes with Allyltrimethylsilanes

Cationic cobalt porphyrin-catalyzed allylation of aldehydes with allyltrimethylsilanes is developed. The formation of the aldehyde-cobalt porphyrin complex, the key intermediate for the addition of allylsilanes, is confirmed by theoretical studies and syn