7182-10-7

Basic information

• Product Name: 1-(1-Butenyl)piperidine
• Synonyms: 1-(1-Butenyl)piperidine
• CAS NO: 7182-10-7
• Molecular Formula: C₉H₁₇N
• Molecular Weight: 0
• Mol File: 7182-10-7.mol
• Article Data: 3

Chemical Properties

• Boiling Point: 203.3°C at 760 mmHg
• Flash Point: 69.1°C
• Appearance: /
• Density: 0.928g/cm³
• Vapor Pressure: 0.28mmHg at 25°C
• Refractive Index: 1.539
• CAS DataBase Reference: 1-(1-Butenyl)piperidine(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(1-Butenyl)piperidine(7182-10-7)
• EPA Substance Registry System: 1-(1-Butenyl)piperidine(7182-10-7)

Safety Data

• Hazardous Substances Data: 7182-10-7(Hazardous Substances Data)

Usage

Structure

Piperidine derivative with a butenyl group attached to the nitrogen atom

Applications

a. Synthesis of pharmaceuticals
b. Synthesis of agrochemicals
c. Potential use as an insecticide
d. Investigation for treatment of neurological disorders (e.g., Parkinson's disease)

Insecticidal properties

Shown to be promising

Neurological relevance

Ability to modulate dopamine receptors in the brain

Versatility

Range of potential applications in various industries

InChI:InChI=1/C9H17N/c1-2-3-7-10-8-5-4-6-9-10/h3,7H,2,4-6,8-9H2,1H3

Upstream product

• 110-89-4 piperidine 
• 109-74-0 propyl cyanide 
• 123-72-8 butyraldehyde 

Downstream Products

• 69457-10-9 2-(4-chloro-phenylhydrazono)-butyraldehyde 
• 69457-11-0 2-(4-nitro-phenylhydrazono)-butyraldehyde 
• 7062-04-6 2-(4-methoxy-phenylhydrazono)-butyraldehyde 
• 858261-50-4 1-(2,4,6-triethyl-cyclohexa-2,4-dienyl)-piperidine 
• 7013-83-4 Aethylglyoxal-p-tolylhydrazon 
• 7013-85-6 C₂₅H₂₈N₆ 
• 35650-55-6 2-ethyl-5-oxo-hexanal 
• 5204-80-8 2-ethylpent-4-enal 
• 7013-77-6 Phenylhydrazon des Ethylglyoxals 
• 7013-78-7 C₂₂H₂₂N₆ 
• 7013-84-5 3-Chlor-phenylhydrazon d. Ethylglyoxals 
• 90554-57-7 3-Butylidene-2-phenyl-1-pyrroline 
• 90331-06-9 1-tert-Butyl-3-ethyl-4-phenyl-1-aza-1,3-butadiene 
• 73669-44-0 3,5-diethyl-4-phenylpyridine 

Relevant articles and documents

Colloid and nanosized catalysts in organic synthesis: XIV. Reductive amination and amidation of carbonitriles catalyzed by nickel nanoparticles

Hydrogenation of carbonitriles catalyzed by nickel nanoparticles in the presence of primary amines led to the predominant formation of unsymmetrical secondary amines. In the presence of secondary amines hydrogenation of nitrites provided enamines as main products. Hydrogenation of nitriles in the presence of formamide or acetamide afforded formyl or acetyl derivatives of primary amines.

Synthesis of α-Cyanoenamines by Cyanation of α-Bromoimmonium Bromides and Dehydrobromination of β-Bromo-α-(dialkylamino)nitriles

The reaction of α-bromoimmonium bromides 4 with potassium cyanide in dimethylformamide gave rise to β-bromo-α-(dialkylamino)nitriles 5, which were dehydrobrominated in various base solvent systems to afford (E)- and (Z)-α-cyanoenamines 2.An adaption of a previously published preparation of α-cyanoenamines starting from aldehydes via enamines led to an improved, efficient and fast synthesis of the title compounds.