72049-82-2

Basic information

• Product Name: trans-2-(cyanomethyl)-1-(trimethylsiloxy)cyclohexane
• CAS NO: 72049-82-2
• Molecular Weight: 211.379
• Mol File: 72049-82-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: trans-2-(cyanomethyl)-1-(trimethylsiloxy)cyclohexane(CAS DataBase Reference)
• NIST Chemistry Reference: trans-2-(cyanomethyl)-1-(trimethylsiloxy)cyclohexane(72049-82-2)
• EPA Substance Registry System: trans-2-(cyanomethyl)-1-(trimethylsiloxy)cyclohexane(72049-82-2)

Safety Data

• Hazardous Substances Data: 72049-82-2(Hazardous Substances Data)

Upstream product

• 75-77-4 chloro-trimethyl-silane 
• 286-20-4 cyclohexane-1,2-epoxide 
• 75-05-8 acetonitrile 

Downstream Products

• 6126-53-0 2-(2-oxopropyl)cyclohexanone 

Relevant articles and documents

Convenient Synthesis of Jasmonoid Compounds from γ-(Trimethylsiloxy)butyronitrile

1,4-Dioxygenated compounds 4 are constructed by the addition of a Grignard reagent to γ-(trimethylsiloxy)nitriles 1,2, and 3 and subsequent hydrolysis.Oxidation of 4 with pyridinium chlorochromate or Jones reagent yields compounds 5 which are used to produce cyclopentenones 6.Methyl jasmonate and methyl dihydrojasmonate are made by the conjugate addition of silylated ketene acetal 9 to 6a and 6b, respectively, and subsequent protodesilylation. γ-Jasmolactone is also derived from 4a by oxidation with pyridinium dichromate in DMF followed by reduction with NaBH4 in ethanol.