7205-58-5

Basic information

• Product Name: Benzene, 1-(ethylthio)-4-methoxy-
• CAS NO: 7205-58-5
• Molecular Formula: C9H12OS
• Molecular Weight: 168.26
• Mol File: 7205-58-5.mol
• Article Data: 20

Chemical Properties

• CAS DataBase Reference: Benzene, 1-(ethylthio)-4-methoxy-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-(ethylthio)-4-methoxy-(7205-58-5)
• EPA Substance Registry System: Benzene, 1-(ethylthio)-4-methoxy-(7205-58-5)

Safety Data

• Hazardous Substances Data: 7205-58-5(Hazardous Substances Data)

Upstream product

• 5335-87-5 4,4'-dimethoxyphenyl disulfide 
• 122-52-1 triethyl phosphite 
• 93-89-0 benzoic acid ethyl ester 
• 696-62-8 para-iodoanisole 
• 75-08-1 ethanethiol 
• 106-54-7 p-Chlorothiophenol 
• 106-46-7 para-dichlorobenzene 
• 104-92-7 1-bromo-4-methoxy-benzene 
• 97-93-8 triethylaluminum 
• 98-68-0 4-methoxy-phenyl-sulphonyl chloride 
• 1879-16-9 1-methoxy-4-methylsulfanyl-benzene 
• 74-88-4 methyl iodide 
• 88218-75-1 p-OCH₃C₆H₄SGe(CH₃)3 
• 75-03-6 ethyl iodide 

Downstream Products

• 7205-68-7 1-(ethylsulfinyl)-4-methoxybenzene 
• 1616280-27-3 C₂₉H₂₉N₃O₆S 
• 1616280-24-0 C₃₀H₃₁N₃O₆S 
• 1616280-10-4 5-{5-amino-2-[4-(ethylsulfonyl)phenoxy]phenyl}-1-methylpyrrolidin-2-one 
• 1616280-07-9 5-{5-amino-2-[4-(ethylsulfonyl)phenoxy]-4-iodophenyl}-1-methylpyrrolidin-2-one 
• 1616280-05-7 5-{2-[4-(ethylsulfonyl)phenoxy]-5-nitrophenyl}-1-methylpyrrolidin-2-one 
• 859537-79-4 4-hydroxy-phenyl-ethylsulfone 
• 1616280-18-2 C₂₂H₂₅IN₂O₆S 
• 1616280-16-0 C₂₂H₂₅IN₂O₆S 
• 150811-28-2 1-Methoxy-2-methyl-4-(isopropylthio)benzene 
• 50390-80-2 4-(Ethylthio)-1-methoxy-2-methylbenzene 
• 7205-61-0 1-methoxy-4-<(1-methylethyl)thio>-benzene 
• 74-85-1 ethene 
• 5633-57-8 1-methoxy-4-(phenylsulfanyl)benzene 

Relevant articles and documents

A mild and chemoselective CALB biocatalysed synthesis of sulfoxides exploiting the dual role of AcOEt as solvent and reagent

A mild, chemoselective and sustainable biocatalysed synthesis of sulfoxides has been developed exploiting CALB and using AcOEt with a dual role of more environmentally friendly reaction solvent and enzyme substrate. A series of sulfoxides, including the drug omeprazole, have been synthesised in high yields and with excellent E-factors.

Nickel-Catalyzed Reversible Functional Group Metathesis between Aryl Nitriles and Aryl Thioethers

We describe a new functional group metathesis between aryl nitriles and aryl thioethers. The catalytic system nickel/dcype is essential to achieve this fully reversible transformation in good to excellent yields. Furthermore, the cyanide- and thiol-free reaction shows high functional group tolerance and great efficiency for the late-stage derivatization of commercial molecules. Finally, synthetic applications demonstrate its versatility and utility in multistep synthesis.

Site-Selective C?S Bond Formation at C?Br over C?OTf and C?Cl Enabled by an Air-Stable, Easily Recoverable, and Recyclable Palladium(I) Catalyst

This report widens the repertoire of emerging PdI catalysis to carbon–heteroatom, that is, C?S bond formation. While Pd0-catalyzed protocols may suffer from the formation of poisonous sulfide-bound off-cycle intermediates and lack of selectivity, the mechanistically diverse PdI catalysis concept circumvents these challenges and allows for C?S bond formation (S–aryl and S–alkyl) of a wide range of aryl halides. Site-selective thiolations of C?Br sites in the presence of C?Cl and C?OTf were achieved in a general and a priori predictable fashion. Computational, spectroscopic, X-ray, and reactivity data support dinuclear PdI catalysis to be operative. Contrary to air-sensitive Pd0, the active PdI species was easily recovered in the open atmosphere and subjected to multiple rounds of recycling.