7205-69-8

Basic information

• Product Name: Benzene, 1-chloro-4-(ethylsulfinyl)-
• CAS NO: 7205-69-8
• Molecular Formula: C8H9ClOS
• Molecular Weight: 188.678
• Mol File: 7205-69-8.mol
• Article Data: 12

Chemical Properties

• CAS DataBase Reference: Benzene, 1-chloro-4-(ethylsulfinyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-chloro-4-(ethylsulfinyl)-(7205-69-8)
• EPA Substance Registry System: Benzene, 1-chloro-4-(ethylsulfinyl)-(7205-69-8)

Safety Data

• Hazardous Substances Data: 7205-69-8(Hazardous Substances Data)

Upstream product

• 5120-72-9 p-chlorophenyl ethyl sulfide 
• 97-93-8 triethylaluminum 
• 98-60-2 4-chlorobenzenesulfonyl chloride 
• 74-96-4 ethyl bromide 
• 106-54-7 p-Chlorothiophenol 
• 64-17-5 ethanol 
• 3085-42-5 bis(4-chlorophenyl)sulfoxide 
• 557-18-6 diethylmagnesium 

Downstream Products

• 127721-29-3 1-Chloro-4-(1-chloro-ethanesulfinyl)-benzene 
• 934-73-6 methyl 4-chlorophenyl sulfoxide 
• 7205-75-6 p-Chlorphenyl-1,1-dimethylaethylsulfoxid 
• 16411-16-8 p-chlorophenyl vinyl sulfide 

Relevant articles and documents

Tungstate supported on magnetic ionic liquid-modi?ed graphene oxide as an efficient and recyclable catalyst for the selective oxidation of sulfides

An effective and recyclable catalyst based on tungstate ion immobilization on magnetic ionic liquid modified graphene oxide (WO4@Fe3O4/GO-IL) has been synthesized in this research. The catalyst was characterized by various

Kinetic investigation on the highly efficient and selective oxidation of sulfides to sulfoxides and sulfones with t-BuOOH catalyzed by La2O3

The selective oxidation of various sulfides to sulfoxides by a simple, efficient, and environmentally benign method is of prime focus. In this paper, we have explored a highly efficient protocol for the oxidation of alkyl aryl sulfides to sulfoxides with high selectivities catalyzed by La2O3 in the presence of 70% t-BuOOH solution (water). We obtained predominantly the monooxygenated product. The over oxidation of sulfides to sulfones was not observed under these conditions. The resulting products are obtained in good to excellent yields within a reasonable time without the use of ligands and other additives. The epoxidation of the double bond as well as allylic oxidation are not observed with allyl sulfides. Sulfones can be obtained quantitatively by altering the reaction conditions. The surface morphology and the catalyst reusability were verified by XRD, AFM and SEM techniques. The surface area of the La2O3 was measured using BET isotherms.

Competing reaction pathways from α-halo-α-protioalkyl aryl sulfoxides initiated by organometallic reagents

The reactions of syn-1-haloethyl p-chlorophenyl sulfoxides (halogen = Cl, Br) with main-group organometallic reagents (n-BuMgCl, MeLi, n-BuLi, s-BuLi, and t-BuLi) in THF and PhMe solvents were examined. Product distributions were analyzed to determine the