720715-38-8

Basic information

• Product Name: [(η5-C5H5)Ru(PPh3)(C5H4N-2-CH=N-C6H4-p-H)]PF6
• CAS NO: 720715-38-8
• Molecular Weight: 755.645
• Mol File: 720715-38-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [(η5-C5H5)Ru(PPh3)(C5H4N-2-CH=N-C6H4-p-H)]PF6(CAS DataBase Reference)
• NIST Chemistry Reference: [(η5-C5H5)Ru(PPh3)(C5H4N-2-CH=N-C6H4-p-H)]PF6(720715-38-8)
• EPA Substance Registry System: [(η5-C5H5)Ru(PPh3)(C5H4N-2-CH=N-C6H4-p-H)]PF6(720715-38-8)

Safety Data

• Hazardous Substances Data: 720715-38-8(Hazardous Substances Data)

Upstream product

• 7032-25-9 2-(phenyliminomethyl)pyridine 
• 32993-05-8 chloro(cyclopentadienyl)bis(triphenylphosphine)ruthenium (II) 

Relevant articles and documents

Synthesis and characterization of cyclopentadienylruthenium(II) complexes containing N,N′-donor Schiff base ligands: Crystal and molecular structure of [(η5-C5H5)Ru(C5H 4N-2-CH=N-C6H4-p-OCH3)(PPh 3)]PF6

Complexes of the formulae [(η5-C5H 5)Ru(PPh3)(C5H5N-2-CH=N-C 6H4-p-X)]+ [X=H (2a), CH3 (2b), OCH3 (2c), Cl (2d), NO2 (2e)] and [(η5- C5H5)Ru(PPh3)(C5H 5N-2-CH=N-C6H11)]+ (3) were prepared by reacting para-substituted N-(pyrid-2-ylmethylene)-phenylamines (2-PP) and N-(pyrid-2-ylmethylene)cyclohexylamine (2-PC) with [(η5-C 5H5)Ru(PPh3)2Cl] (1) in methanol. These complexes have been isolated as hexa-fluorophosphate salts. Representative complex 2c has been established by single crystal X-ray diffraction analysis. Complex 2c crystallizes in the orthorhombic space group Pbcn, with a=21.1560 (11) A?, b=18.3972 (9) A? and c=17.5130 (9) A?, V=6816.3 (6) A?3 and z=8. All these complexes were characterized by FT-IR, 1H NMR and 31P{1H} NMR spectroscopy.