721-47-1Relevant articles and documents
Effect of a rigid sulfonamide bond on molecular folding: A case study
Suhonen, Aku,Morgan, Ian S.,Nauha, Elisa,Helttunen, Kaisa,Tuononen, Heikki M.,Nissinen, Maija
, p. 2602 - 2608 (2015)
A disulfonamide compound with bulky aromatic side chains was prepared, and its properties as a potential building block for foldamers were evaluated. Two different solvate crystal forms of the compound were identified and compared to the structures of an
Insight into Fundamental Rules of Phenylenediamines Selective Monoacylation by the Comparisons of Kinetic Characteristics in Microreactor
Xu, Qilin,Liu, Ji Ming,Yao, Hongmiao,Zhao, Jinyang,Wang, Zhikuo,Liu, Junli,Zhou, Jiadi,Yu, Zhiqun,Su, Weike
supporting information, p. 1336 - 1344 (2021/08/06)
In this paper, the kinetics of acylation reaction of o-phenylenediamine/p-phenylenediamine and benzoic anhydride were determined in microreactors, respectively. A kinetic model was established, all kinetic parameters including reaction orders, reaction rate constants, pre-exponential factors, and activation energies were acquired. Validation experiments showed experimental data fit well with calculated data at different reactant concentrations and residence times. The comparisons of the reaction rate constants and activation energies were summarized to show the difference of chemical reactivities of phenylenediamines. According to the calculation of the kinetic model, the optimized reaction conditions were listed to meet the monoacylation selectivity equal to 97.0%.
[Re(η6-C6H5-benzimidazole)2]+ and Derivatives as Dye Mimics; Synthesis, UV Absorption Studies and DFT Calculations
Gotzmann, Carla,Blacque, Olivier,Fox, Thomas,Alberto, Roger
supporting information, p. 2493 - 2498 (2021/06/01)
Functionalizations of highly oxidation and hydrolysis stable mono-cationic rhenium bis-arene complexes [Re(η6-C6H6)2]+ are of great interest. We directly built up structural features of the well-known Hoechst Dye on the coordinated arenes as a model for prospective DNA minor groove binding studies. Extensions of the aromatic bis-arene unit with functionalized and derivatized benzimidazole moieties resulted in a deep orange colour of the complexes, showing UV/Vis absorption spectra with multiple transition maxima. These have been assigned with support of DFT calculations to gain information about their charge transfer natures. The different transitions of the complexes, which are either intra-ligand, ligand-to-ligand or metal-to-ligand charge transitions, were additionally compared and discussed with the spectra of the corresponding free ligands.