72117-54-5Relevant articles and documents
Synthesis, spectroscopy and structure of phenylated cyclopentasilanes
P?schl, Ulrich,Siegl, Harald,Hassler, Karl
, p. 93 - 100 (2007/10/02)
Phenylated cyclopentasilanes Si5Ph10-nXn with X = OSO2CF3, F, Cl, Br, I or H and n = 1 or 2 were prepared in high yield by dearylation of Si5Ph10 with trifluoromethanesulphonic acid (CF3SO3H) and subsequent reaction with lithium or potassium halides and LiAlH4. The trans-1,3-isomers of Si5Ph8X2 were isolated by crystallization and the crystal structure of trans-1,3-difluorooctaphenyl- cyclopentasilane was determined. cis-1,3-, trans-1,2- and cis-1,2-Si5Ph8X2 were identified and characterized by 1H, 19F and 29Si NMR spectroscopy. Si-Si coupling constants were measured using INADEQUATE pulse sequences.