7213-64-1Relevant articles and documents
UNTERSUCHUNGEN ZUM THERMISCHEN UND PHOTOCHEMISCHEN VERHALTEN VON 8,9-DIAZA-4,5-BENZOTRICYCLO3,7>OCTA-4,8-DIEN
Erden, Ihsan,Balci, Metin
, p. 1825 - 1828 (1980)
Die direkte Photolyse der Titelverbindung 1 verlaeuft erwartungsgemaess unter Stickstoffabspaltung zu 6.Dagegen fuehrt ihre Thermolyse und ihre sensibilisierte Bestrahlung zu den ueberraschenden Produkten 4 bzw. 8, deren spektroskopische Charakterisierung und moegliche Bildungsmechanismen diskutiert werden.
LIGHT-MEDIATED TRANSFORMATIONS OF OLEFINS INTO ALCOHOLS: REACTIONS OF HYDROXYL RADICALS WITH CYCLOALKENES
Sonawane, H. R.,Nanjundiah, B. S.,Kelkar, R. G.
, p. 6673 - 6682 (2007/10/02)
Reactions of hydroxyl radicals, generated by photodecomposition of hydrogen peroxide in acetonitrile, with a wide variety of cycloalkenes have been examined.The results show that the major reaction is the addition of hydroxyl radicals to the less substituted end of the double bond, furnishing the secondary alcohols.The reactivity pattern and the observed regio- and stereoselectivity clearly reveal that the steric parameters associated with the substrates play a dominant role in directing the addition reactions.More importantly, this study led to the development of a new methodology for the facile conversions of olefins essentially into secondary alcohols, and includes a few examples which demonstrate the potential of the method.
PHOTOCHEMISTRY OF BENZOTRICYCLO2,7>HEPTENE: SINGLET EXCITED STATE REACTIONS DERIVED FROM CYCLOPROPANE RING CLEAVAGE
Johnson, Richard P.,Davis, Katherine Schlimgen
, p. 3171 - 3174 (2007/10/02)
Direct irradiation of the title hydrocarbon in cyclohexane affords 2-vinylindene and benzonorcaradiene as major primary photoproducts.Deuterium labeling is used to determine reaction mechanisms.