7214-33-7

Basic information

• Product Name: Cyclohexane, 1-(1,1-dimethylethyl)-4-nitro-, cis-
• CAS NO: 7214-33-7
• Molecular Formula: C10H19NO2
• Molecular Weight: 185.266
• Mol File: 7214-33-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Cyclohexane, 1-(1,1-dimethylethyl)-4-nitro-, cis-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexane, 1-(1,1-dimethylethyl)-4-nitro-, cis-(7214-33-7)
• EPA Substance Registry System: Cyclohexane, 1-(1,1-dimethylethyl)-4-nitro-, cis-(7214-33-7)

Safety Data

• Hazardous Substances Data: 7214-33-7(Hazardous Substances Data)

Upstream product

• 82992-54-9 c-4-t-butyl-r-1-chloro-1-nitrocyclohexane 
• 4701-98-8 4-tert-butylcyclohexanone oxime 
• 53255-92-8 4-t-butyl-aci-nitrocyclohexane 

Relevant articles and documents

The Photochemistry of α,β-Unsaturated Nitro Compounds and Nitronic Acids. Concerning Deconjugation and α,β-Unsaturated Ketone Formation

The photochemistry of cyclohexylidenenitromethane (6), 3-ethyl-2-nitropent-2-ene (7), (Z)-α-methyl-α'-nitrostilbene (12), (E)-3-methyl-1-nitro-1-phenylbut-1-ene (15) and 4,4-dimethyl-3-nitro-5α-cholest-2-ene (27) has been examined to determine the structural features required for deconjugation to the β,γ-unsaturated isomer.The mechanism of the light-induced formation of the corresponding α,β-unsaturated ketone, which may accompany deconjugation, has also been examined.Support for a scheme involving γ-hydrogen abstraction to give an unsaturated nitronic acid, followed by N-hydroxyoxaziridine formation and collapse to the ketone, is provided in the photochemistry of the stable nitronic acids, 4-t-butyl-aci-nitrocyclohexane (17) and 9-aci-nitrofluorene (18).Syntheses of the nitro olefins (6), (7), (12), (15) and (27), and the nitronic acid (17) are also reported.