7228-12-8

Basic information

• Product Name: 5-Methylhex-5-enyl toluene-p-sulfonate
• CAS NO: 7228-12-8
• Molecular Weight: 268.377
• Mol File: 7228-12-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 5-Methylhex-5-enyl toluene-p-sulfonate(CAS DataBase Reference)
• NIST Chemistry Reference: 5-Methylhex-5-enyl toluene-p-sulfonate(7228-12-8)
• EPA Substance Registry System: 5-Methylhex-5-enyl toluene-p-sulfonate(7228-12-8)

Safety Data

• Hazardous Substances Data: 7228-12-8(Hazardous Substances Data)

Upstream product

• 5212-80-6 5-methylhex-5-en-1-ol 
• 98-59-9 p-toluenesulfonyl chloride 
• 928-90-5 5-hexyl-1-ol 

Downstream Products

• 5212-67-9 6-methyl-hept-6-enoic acid 
• 5212-71-5 7-methyl-7-octenoic acid 
• 6887-97-4 6-Methylhept-6-enenitrile 

Relevant articles and documents

Oxygen to carbon rearrangements of anomerically linked alkenols from tetrahydropyran derivatives: An investigation of the reaction mechanism via a double isotopic labelling crossover study

A variety of alkenol tetrahydropyran derivatives were prepared and subjected to a tin tetrachloride promoted anomeric oxygen to carbon rearrangement. Using this methodology many of the corresponding carbon-linked structures were synthesised, including alkenes and bicyclic ethers, in good yields. On the basis of an isotopic labelling study using 2H incorporated into the side chain and ring system it is proposed that these reactions proceed via an intermodular pathway. The Royal Society of Chemistry 2000.