72395-46-1Relevant articles and documents
4? + 2? Cycloadditions to P-Chlorobis(trimethylsilyl)methylenephosphine: New Cyclic Compounds with a >C=P-Double Bond
Ko, Yeung Y. C. Yeung Lam,Carrie, Robert
, p. 1640 - 1641 (1984)
The reaction of P-chlorobis(trimethylsilyl)methylenephosphine with several 1,3-dipoles and two dienes gives cycloadducts regiospecifically, these will eliminate Me3SiCl at low temperatures if the resulting compound is of an 'aromatic' type, leading to new cyclic >C=P- double bond derivatives.
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Gilliam,Sauer
, p. 1793 (1944)
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Lee
, p. 321 (1969)
Preparation and Crystal Structure of Cu4iP-CH2-PPri2>Cl3(Py)2 (Py=pyridine): A Novel Copper Complex with a Triply Bridging Secondary Phosphido Group μ-PRR' i; R'=CH2-PPri2>
Brauer, David J.,Knueppel, Peter C.,Stelzer, Othmar
, p. 551 - 552 (1988)
The first copper complex Cu4(PriP-CH2-PPri2)Cl3(Py)2 (Py=pyridine) containing a triply bridging secondary phosphido group μ-PRR' has been synthesized and characterized by X-ray crystallography.
A NOVEL APPROACH TO THE SYNTHESIS OF DEOXYNUCLEOSIDE PHOSPHOROFLUORIDATES - II.
Dabkowski, Wojciech,Cramer, Friedrich,Michalski, Jan
, p. 3301 - 3302 (1988)
Trimethylsilyl esters of general formula RR'POSiMe3 derived from nucleosides react in quantitative and fully chemoselective way with sulphuryl chloride fluoride to give nucleoside fluorophosphates of high purity under extremely mild conditions
Sauer,Scheiber,Hadsell
, p. 4254 (1948)
Intramolecular base-stabilised adducts of main group halides
Aldridge, Simon,Calder, Richard J.,Coombs, Deborah L.,Jones, Cameron,Steed, Jonathan W.,Coles, Simon,Hursthouse, Michael B.
, p. 677 - 686 (2002)
The coordination chemistry of alkoxo and amido ligands bearing pendant nitrogen or sulfur donors has been developed to include examples of main group complexes. The structural implications of amido ligand coordination augmented by a tethered pyridyl base have been investigated for group 13 and 14 derivatives {[6-(Me3SiN)-2-Me-C5H3N]SnCl3 and [6-(Me3SiN)-2-Me-C5H3N]BBr2}. Furthermore, the scope, kinetics and mechanism of the synthesis of alkoxo and amido derivatives from trimethylsilyl substituted precursors have been investigated in depth. The methodology is found to be applicable to a range of ligand frameworks of varying flexibility, stabilised by one or two "tether" arms.
Triplet-state photoreactivity of phenyldisilanes
Leigh, William J.,Sluggett, Gregory W.
, p. 7531 - 7532 (1993)
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Narula, Chaitanya K.,Schaeffer, Riley,Paine, Robert T.,Datye, Abhaya,Hammetter, William F.
, p. 5556 - 5557 (1987)
Reaction of alkali metal dibutylboron with alkyl halides in diethyl ether solution
Pasto, Daniel J.,Wojtkowski, Paul W.
, p. 251 - 257 (1972)
The reaction of alkali metal dibutylboron (I), prepared by the treatment of dibutylchloroborane with sodium/potassium alloy in diethyl ether, with alkyl iodides has been studied. Very little alkylation on boron to produce dibutylalkylborane occurs in ethe
Reactions of N,N′-dimethyl-N,N′-bis(trimethylsilyl)-methylphosphonic diamide with chloral and chloromethyldimethylchlorosilane
Pudovik,Kibardina,Zyablikova,Pudovik
, p. 327 - 329 (2001)
N,N′-Dimethyl-N,N′-bis(trimethylsilyl)methylphosphonic diamide reacts with chloral to form 1,2,3-trimethyl-4,4-dichloro-5-trimethylsiloxy-1,3,2-diazaphospholidine 2-oxide and with chloromethyldimethylchlorosilane to form 1,2,3,4,4-pentamethyl-1,3-diaza-2-
A General and Selective Synthesis of Methylmonochlorosilanes from Di-, Tri-, and Tetrachlorosilanes
Naganawa, Yuki,Nakajima, Yumiko,Sakamoto, Kei
supporting information, p. 601 - 606 (2021/01/13)
Direct catalytic transformation of chlorosilanes into organosilicon compounds remains challenging due to difficulty in cleaving the strong Si-Cl bond(s). We herein report the palladium-catalyzed cross-coupling reaction of chlorosilanes with organoaluminum reagents. A combination of [Pd(C3H5)Cl]2 and DavePhos ligand catalyzed the selective methylation of various dichlorosilanes 1, trichlorosilanes 5, and tetrachlorosilane 6 to give the corresponding monochlorosilanes.
SYNTHESIS OF ORGANO CHLOROSILANES FROM ORGANOSILANES
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Page/Page column 36; 37, (2019/04/16)
The invention relates to a process for the production of chlorosilanes by subjecting one or more hydndosilanes to the reaction with hydrogen chloride in the presence of at least one ether compound, and a process for the production of such hydndosilanes serving as starting materials.
A preparation method of the trimethyl chlorosilane (by machine translation)
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Paragraph 0020-0033, (2019/05/02)
The invention provides a preparation method of the trimethyl chlorosilane, six-hexamethyl disilane, double-(trichloromethyl) carbonate, catalyst is added to the solvent, thereby obtaining a reaction mixture, said reaction mixture is added to the initiator, the reaction is carried out, after the reaction is finished after treatment can get trimethylchlorosilane. The method of the invention is safe and controllable, and easy to operate, is friendly to the environment, the resulting high purity of the product, by-product is only carbon dioxide gas, the elimination of industrial production in significant corrosion source - hydrogen chloride, greatly improve the working environment in the production process, and the solvent, catalyst and initiator can be used repeatedly, is a green-friendly chlorination process, has wide industrial application prospect, is suitable for application. (by machine translation)