72429-31-3

Basic information

• Product Name: N⁴-benzoyl-3',5'-di-O-tert-butyldimethylsilylcytidine
• Synonyms: N⁴-benzoyl-3',5'-di-O-tert-butyldimethylsilylcytidine
• CAS NO: 72429-31-3
• Molecular Weight: 575.853
• Mol File: 72429-31-3.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: N⁴-benzoyl-3',5'-di-O-tert-butyldimethylsilylcytidine(CAS DataBase Reference)
• NIST Chemistry Reference: N⁴-benzoyl-3',5'-di-O-tert-butyldimethylsilylcytidine(72429-31-3)
• EPA Substance Registry System: N⁴-benzoyl-3',5'-di-O-tert-butyldimethylsilylcytidine(72429-31-3)

Safety Data

• Hazardous Substances Data: 72429-31-3(Hazardous Substances Data)

Upstream product

• 18162-48-6 tert-butyldimethylsilyl chloride 
• 13089-48-0 N₄-benzoylcytidine 

Downstream Products

• 82845-97-4 N⁴-benzoyl-1-[3',5'-bis-O-(tert-butyldimethylsilyl)-β-D-arabinofuranosyl]cytosine 
• 87865-90-5 N-{1-[(2R,3R,4R,5R)-4-Hydroxy-5-[(4-methoxy-phenyl)-diphenyl-methoxymethyl]-3-(tetrahydro-furan-2-yloxy)-tetrahydro-furan-2-yl]-2-oxo-1,2-dihydro-pyrimidin-4-yl}-benzamide 
• 88160-14-9 C₄₆H₄₅Cl₂N₅O₁₃P₂ 
• 88182-45-0 3',5'-O-diacetyl-2'-O-tetrahydrofuranyl-N-benzoylcytidine 
• 90865-72-8 2'-O-Tetrahydrofuranyl-4-N-benzoylcytidine 
• 72409-39-3 N⁴-benzoyl-O^3'-(tert-butyl-dimethyl-silanyl)-cytidine 

Relevant articles and documents

The S,X-acetals in nucleoside chemistry: II. The synthesis of 3′-O-methylthiomethylribonucleosides

3′-O-Methylthiomethyl derivatives of ribonucleosides were synthesized from the selectively protected nucleosides by the action of a dimethyl sulfide-benzoyl peroxide mixture in acetonitrile or a dimethyl sulfoxide-acetic anhydride-acetic acid mixture.

New catalists and procedures for the dimethoxytritylation and selective silylation of ribonucleosides

Procedures have been developed for the selective formation of (a) 2',5'-silylated ribonucleosides and (b) 3',5'-silylated ribonucleosides.These procedures also permit the selective silylation at either the 2'- or 3'-position of dimethoxytritylated ribonuc

NITRATE ION AS CATALYST FOR SELECTIVE SILYLATIONS OF NUCLEOSIDES

Nitrate ion has been found to have a remarkable effect on the selectivity of silylation of ribonucleosides using the t-butyldimethylsilyl group.