72653-51-1

Basic information

• Product Name: 2-(1-phenylthio-2-methylpropyl)cyclohexanone
• Synonyms: 2-(1-phenylthio-2-methylpropyl)cyclohexanone
• CAS NO: 72653-51-1
• Molecular Weight: 262.416
• Mol File: 72653-51-1.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 2-(1-phenylthio-2-methylpropyl)cyclohexanone(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(1-phenylthio-2-methylpropyl)cyclohexanone(72653-51-1)
• EPA Substance Registry System: 2-(1-phenylthio-2-methylpropyl)cyclohexanone(72653-51-1)

Safety Data

• Hazardous Substances Data: 72653-51-1(Hazardous Substances Data)

Upstream product

• 108-94-1 cyclohexanone 
• 13307-61-4 Isobutylthiobenzene 
• 6651-36-1 1-(Trimethylsilyloxy)cyclohexene 
• 55999-41-2 (1-Acetoxy-isobutyl)-phenyl-sulfid 
• 72653-48-6 α-chloroisobutyl phenyl sulfide 

Downstream Products

• 66806-69-7 2-Isobutylidenecyclohexanone 
• 4668-64-8 2-(2-methylpropyl)cyclohexanone 

Relevant articles and documents

The synthesis of α-acetoxy sulfides and their Lewis acid-mediated reactions

α-Acetoxy sulfides can be conveniently prepared by the reaction of dithioacetals with mercuric acetate at ambient temperature. They react with allyltrimethylsilane, enol silyl ethers, and cyanotrimethylsilane in the presence of SnCl4 to afford

α-Alkylation and α-alkylidenation of carbonyl compounds: Lewis acid-promoted phenylthioalkylation of o-silylated enolates

The O-silylated enolates of ketones, aldehydes, esters, and lactones can be phenylthioalkylated in the presence of Lewis acids; reductive or oxidative sulphur-removal gives the regiospecifically α-alkylated or alkylidenated carbonyl compounds.