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7275-43-6

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7275-43-6 Usage

Description

2,2'-Dipyridyl N,N'-dioxide, also known as 2,2'-bipyridyl-N,N'-dioxide or bipyO2, is a chemical compound with complexation abilities as a ligand towards various metal ions, including zinc and lanthanides such as Eu3+, Tb3+, Gd3+, Sm3+, and Dy3+. It has been synthesized and characterized through elemental analysis and IR spectrum, and its electron density has been studied in a halogen-bonded complex with 1,4-diiodotetrafluorobenzene (F4dIb) at 90K using X-ray diffraction.

Uses

Used in Chemical Complexation:
2,2'-Dipyridyl N,N'-dioxide is used as a ligand for complexation with metal ions, particularly zinc and lanthanides, due to its ability to form stable complexes with these elements. This property makes it useful in various chemical applications, such as the synthesis of novel lanthanide complexes.
Used in X-ray Diffraction Studies:
The electron density of halogen-bonded complexes involving 2,2'-dipyridyl N,N'-dioxide, such as the one with 1,4-diiodotetrafluorobenzene (F4dIb), has been studied at 90K using X-ray diffraction. This application allows researchers to gain insights into the structural and electronic properties of these complexes, which can be valuable for understanding their behavior and potential uses in various fields.

Check Digit Verification of cas no

The CAS Registry Mumber 7275-43-6 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 7,2,7 and 5 respectively; the second part has 2 digits, 4 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 7275-43:
(6*7)+(5*2)+(4*7)+(3*5)+(2*4)+(1*3)=106
106 % 10 = 6
So 7275-43-6 is a valid CAS Registry Number.
InChI:InChI=1/C10H8N2O2/c13-11-7-3-1-5-9(11)10-6-2-4-8-12(10)14/h1-8H

7275-43-6 Well-known Company Product Price

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  • TCI America

  • (B3859)  2,2'-Bipyridyl 1,1'-Dioxide  >98.0%(HPLC)(T)

  • 7275-43-6

  • 5g

  • 790.00CNY

  • Detail
  • Aldrich

  • (364177)  2,2′-DipyridylN,N′-dioxide  98%

  • 7275-43-6

  • 364177-1G

  • 497.25CNY

  • Detail

7275-43-6SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017

1.Identification

1.1 GHS Product identifier

Product name 2,2'-DIPYRIDYL N,N'-DIOXIDE

1.2 Other means of identification

Product number -
Other names 2,2'-bipyridine-N,N'-dioxide

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:7275-43-6 SDS

7275-43-6Relevant articles and documents

Syntheses, crystal structure, and magnetic properties of a self-assembling dicopper(II) helicate with novel bipyridine ligand

Kao, Hsien-Chang,Wang, Yi-Chun,Wang, Wen-Jwu

, p. 934 - 939 (2012)

Anovel double helical dicopper(II) complex was synthesized by reaction of a polydentate ligand L = 2,2'- bipyridyl-6,6'-bis(2-acetylpyrazinohydrazone) with copper(II) perchlorate in CH3CN. The self-assembling process was studied by UV-Vis spectrometric titration experiments which revealed the formation of dinuclear complexes [Cu2L2](ClO 4)4. The structure of dicopper double-helicate was confirmed by X-ray diffractometry. Each copper(II) center occupies a distorted octahedral environment. Variable-temperature magnetic measurements reveal weak antiferromagnetic interactions between Cu(II) ion centers with J = -0.63 cm -1.

Models of molecular photocatalysts for water oxidation: Strategies for conjugating the Ru(bda) fragment (bda = 2,2′-bipyridine-6,6′-dicarboxylate) to porphyrin photosensitizers

Adamo, F.,Alessio, E.,Iengo, E.,Vidal, A.

supporting information, (2020/12/09)

Model dyads, in which the Ru(bda) water oxidation catalyst (WOC) is connected to a porphyrin, were prepared following two different modular strategies: i) the direct linkage approach, in which porphyrins bearing peripheral pyridyl rings are bound to the {

The M?CPbA?NH3(G) system: A safe and scalable alternative for the manufacture of (substituted) pyridine and quinoline N?oxides?

Palav, Amey,Misal, Balu,Ernolla, Anilkumar,Parab, Vinod,Waske, Prashant,Khandekar, Dileep,Chaudhary, Vinay,Chaturbhuj, Ganesh

supporting information, p. 244 - 251 (2019/03/17)

An improved, safe, and scalable isolation process for (substituted) pyridine and quinoline N-oxides in quantitative yields along with high purities using the m-CPBA?NH3(g) system is described. The safety was assessed by reaction calorimetry and differential scanning calorimetry studies for possible hazards during the conversion and isolation steps. Careful interpretation of the data substantiated the safety and scalability. The process flow is simplified to meet the industrial requirements of safety, cost-effectiveness, and utility minimization. The reaction was safely demonstrated at a 2.5 kg scale.

The synthesis of diethyl 2-(2,2 ′ -bipyridin-4-ylmethylene)malonate and diethyl 3,3 ′ -(2,2 ′ -bipyridine-4,4 ′ -diyl)diacrylate

Heintz, Katharina,G?rls, Helmar,Imhof, Wolfgang

, (2018/06/15)

Abstract: The new acrylic acid derivatives diethyl 2-(2,2′-bipyridin-4-ylmethylene)malonate and diethyl 3,3′-(2,2′-bipyridine-4,4′-diyl)diacrylate which may be used for the introduction of metal coordination sites in polyacrylates were synthesized and characterized. Intermediates of the syntheses were prepared by improved synthetic protocols working under microwave conditions whenever it was advantageous for the resulting product in terms of reaction time and/or chemical yield. In addition, the crystal structure of one of the intermediates, 4,4′-dibromo-2,2′-bipyridine (6), is reported, in which molecules are arranged into infinite chains by C-H—Br interactions. Graphical Abstract: SYNOPSIS Synthesis and characterization of new 2,2’-bipyridine ligands with substituents related to acrylic acid esters are reported. These compounds offer the possibility to incorporate 2,2’-bipyridine ligands or coordination compounds derived from them into polyacrylate materials. [Figure not available: see fulltext.].

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