7287-36-7 Usage
Description
MONALIDE is a herbicidal compound used for the control of broad-leaved weeds in various crops.
Uses
Used in Crop Protection Industry:
MONALIDE is used as a preemergence and postemergence herbicide for the control of broad-leaved weeds in crops such as parsley, carrots, dill, and celery. It helps to protect these crops from weed competition, ensuring healthy growth and higher yields.
Used in Vegetable Production:
MONALIDE is used as a weed control agent in the production of vegetables like carrots, celery, and parsley. It helps to eliminate weeds that can compete with these vegetables for nutrients, water, and sunlight, leading to improved crop quality and productivity.
Environmental Fate
Biological. In the presence of suspended natural populations from unpolluted aquatic
systems, the second-order microbial transformation rate constant determined in the laboratory
was reported to be 6 ′ 10–13 L/organisms-hour (Steen, 1991).Soil. Probably degrades via ring hydroxylation and subsequent ring cleavage. Persistence
in soil is limited to approximate 6–8 weeks (Hartley and Kidd, 1987). Under
laboratory conditions, the half-lives in soil were 30, 48 and 59 days at pH 4.85,
Check Digit Verification of cas no
The CAS Registry Mumber 7287-36-7 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 7,2,8 and 7 respectively; the second part has 2 digits, 3 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 7287-36:
(6*7)+(5*2)+(4*8)+(3*7)+(2*3)+(1*6)=117
117 % 10 = 7
So 7287-36-7 is a valid CAS Registry Number.
InChI:InChI=1/C13H18ClNO/c1-4-9-13(2,3)12(16)15-11-7-5-10(14)6-8-11/h5-8H,4,9H2,1-3H3,(H,15,16)
7287-36-7Relevant articles and documents
Palladium-Catalyzed Markovnikov Hydroaminocarbonylation of 1,1-Disubstituted and 1,1,2-Trisubstituted Alkenes for Formation of Amides with Quaternary Carbon
Yang, Hui-Yi,Yao, Ya-Hong,Chen, Ming,Ren, Zhi-Hui,Guan, Zheng-Hui
supporting information, p. 7298 - 7305 (2021/05/26)
Hydroaminocarbonylation of alkenes is one of the most promising yet challenging methods for the synthesis of amides. Herein, we reported the development of a novel and effective Pd-catalyzed Markovnikov hydroaminocarbonylation of 1,1-disubstituted or 1,1,2-trisubstituted alkenes with aniline hydrochloride salts to afford amides bearing an α quaternary carbon. The reaction makes use of readily available starting materials, tolerates a wide range of functional groups, and provides a facile and straightforward approach to a diverse array of amides bearing an α quaternary carbon. Mechanistic investigations suggested that the reaction proceeded through a palladium hydride pathway. The hydropalladation and CO insertion are reversible, and the aminolysis is probably the rate-limiting step.