72897-05-3

Basic information

• Product Name: 1,3,5-triphenyl-1,3,5-diazaphosphinane
• Synonyms: 1,3,5-Diazaphosphorine, hexahydro-1,3,5-triphenyl-; 1,3,5-Triphenyl-1,3,5-diazaphosphinane
• CAS NO: 72897-05-3
• Molecular Formula: C₂₁H₂₁N₂P
• Molecular Weight: 332.3786
• Mol File: 72897-05-3.mol
• Article Data: 3

Chemical Properties

• Boiling Point: 511.5°C at 760 mmHg
• Flash Point: 263.2°C
• Vapor Pressure: 1.4E-10mmHg at 25°C
• CAS DataBase Reference: 1,3,5-triphenyl-1,3,5-diazaphosphinane(CAS DataBase Reference)
• NIST Chemistry Reference: 1,3,5-triphenyl-1,3,5-diazaphosphinane(72897-05-3)
• EPA Substance Registry System: 1,3,5-triphenyl-1,3,5-diazaphosphinane(72897-05-3)

Safety Data

• Hazardous Substances Data: 72897-05-3(Hazardous Substances Data)

Upstream product

• 3127-08-0 bis(hydroxymethyl)phenylphosphine 
• 62-53-3 aniline 
• 50-00-0 formaldehyd 
• 72936-83-5 bis(phenylaminomethyl)phenylphosphine 

Downstream Products

• 174321-06-3 (1,3,5-triphenyl-1,3,5-diazaphosphorinane)pentacarbonyltungsten 
• 145957-04-6 cis-{bis(1,3,5-triphenyl-1,3,5-diazaphosphorinane)}dichloropalladium(II) 
• 134097-08-8 {C₃H₆N₂P(C₆H₅)3}2NiCl₂ 
• 134097-07-7 {C₃H₆N₂P(C₆H₅)3}2CoCl₂ 
• 181963-80-4 {C₃H₆N₂P(C₆H₅)3}2PtCl₂ 
• 141780-57-6 (1,3,5-triphenyl-1,3,5-diazaphosphorinane)pentacarbonylmolybdenum(O) 
• 74607-62-8 5-phenyl-5-oxo-1,3-diphenyl-1,3,5-diazaphosphorinane 
• 75593-74-7 1,3,5,7-tetraphenyl-1,5-diaza-3,7-diphosphacyclooctane 

Relevant articles and documents

SYNTHESIS AND PROPERTIES OF TRIETHYLAMMONIUM 2,2,5-TRIPHENYL-1,3,2,5-DIOXABORATAPHOSPHORINANE

The reaction of bis(hydroxymethyl)phenylphosphine with isobutyl diphenylborate in the presence of triethylamine leads to the formation of triethylammonium 2,2,5-triphenyl-1,3,2,5-dioxaborataphosphorinane (1).The reaction of compound 1 with electrophilic reagents (O, S, Se, CH2O, RHal) leds to quaternization of the phosphorus atom, giving the corresponding phosphine oxides, sulfides, and selenides and P,B-containing betaines.In the reactions of compound 1 with amines aminomethylphosphines of the diazaphosphorinane and diazadiphosphacyclooctane series are formed.Ammonium 1,3,2,5-dioxaborataphosphorinanes dissociate in solution and enter into ion exchange with phosphonium iodides, leading to phosphonium 1,3,2,5-dioxaborataphosphorinanes.The latter, in the case of the aminomethylphosphonium cation, undergo intramolecular rearrangement with the formation of P,B-containing betaines and aminomethylphosphines. Keywords: Triethylammonium 2,2,5-triphenyl-1,3,2,5-dioxaborataphosphorinane, oxide, sulfide, aminomethylphosphine, ion exchange, triphenylmethylphosphonium 1,3,2,5-dioxaborataphosphorinane.

ORIENTATION OF PHENYL GROUP ATTACHED TO PHOSPHORUS ATOM IN 5-PHENYL-1,3-DI-R-1,3,5-DIAZAPHOSPHORINANES

-