73039-26-6

Basic information

• Product Name: N,N'-bis(trimethylsilyl)-N,N-diphenyl-4,4'-phenylendiamine
• Synonyms: N,N'-bis(trimethylsilyl)-N,N-diphenyl-4,4'-phenylendiamine
• CAS NO: 73039-26-6
• Molecular Weight: 404.702
• Mol File: 73039-26-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N,N'-bis(trimethylsilyl)-N,N-diphenyl-4,4'-phenylendiamine(CAS DataBase Reference)
• NIST Chemistry Reference: N,N'-bis(trimethylsilyl)-N,N-diphenyl-4,4'-phenylendiamine(73039-26-6)
• EPA Substance Registry System: N,N'-bis(trimethylsilyl)-N,N-diphenyl-4,4'-phenylendiamine(73039-26-6)

Safety Data

• Hazardous Substances Data: 73039-26-6(Hazardous Substances Data)

Upstream product

• 75-77-4 chloro-trimethyl-silane 
• 74-31-7 N,N'-diphenyl-1,4-phenylenediamine 

Downstream Products

• 14118-16-2 N,N,N',N'-tetraphenyl-p-phenylenediamine 

Relevant articles and documents

Silicon-based CN cross-coupling reaction

Palladium-catalyzed CN bond-forming cross-coupling reaction of N-trimethylsilylamines with aryl bromides and chlorides is found to proceed in the presence of a fluoride activator in 1,3-dimethyl-2-imidazolidinone (DMI), giving triarylamines in excellent yields. When aryl bromide and bis(silyl)amine were used in this reaction, double CN bondforming products were obtained in high yields. The present reaction was successfully applied to CN bond-forming polymerization.