73039-27-7

Basic information

• Product Name: naphthalen-1-yl-phenyl-trimethylsilylamine
• Synonyms: naphthalen-1-yl-phenyl-trimethylsilylamine
• CAS NO: 73039-27-7
• Molecular Weight: 291.468
• Mol File: 73039-27-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: naphthalen-1-yl-phenyl-trimethylsilylamine(CAS DataBase Reference)
• NIST Chemistry Reference: naphthalen-1-yl-phenyl-trimethylsilylamine(73039-27-7)
• EPA Substance Registry System: naphthalen-1-yl-phenyl-trimethylsilylamine(73039-27-7)

Safety Data

• Hazardous Substances Data: 73039-27-7(Hazardous Substances Data)

Upstream product

• 75-77-4 chloro-trimethyl-silane 
• 90-30-2 N-phenyl-1-naphthylamine 

Downstream Products

• 138310-86-8 N-(4-methylphenyl)-N-phenylnaphthalen-1-amine 
• 123847-85-8 4,4'-bis[N-(1-naphthyl)-N-phenylamino] biphenyl 

Relevant articles and documents

Palladium catalysed aryl amination reactions in supercritical carbon dioxide

Palladium catalysed C-N bond formation in supercritical carbon dioxide has been accomplished. Carbamic acid formation is avoided in part through the use of an N-silylamine as the coupling partner. Employing a catalyst system of Pd 2dba3 (1 mol%) and 2-dicyclohexylphosphino-2′, 4′,6′-triisopropyl-1,1′-biphenyl (X-Phos) (2 mol%) enabled the catalytic amination of aryl bromides and chlorides with N-silylanilines to be realised in excellent yield. Extension of the methodology to the N-arylation of N-silyldiarylamines, N-silylazoles and N-silylsulfonamides is reported. The Royal Society of Chemistry 2005.