73041-05-1Relevant articles and documents
ISOMERIC TRANSFORMATIONS OF INTERNAL PERFLUORINATED α-OXIDES
Zapevalov, A.Ya.,Filyakova, T.I.,Kolenko, I.P.,Kodess, M.I.
, p. 80 - 85 (2007/10/02)
The isomeric transformation of the oxides of internal perfluorinated olefins into ketones by the action of alkali-metal fluorides and antimony pentafluoride were studied.The direction of opening of the α-oxide ring in the unsubstituted perfluorinated olefins in the presence of alkali-metal fluorides is determined largely by steric factors.Opening of the epoxide ring by the action of antimony pentafluoride is equally probable in both possible directions.