7318-82-3Relevant articles and documents
Hydroboration with haloborane/trialkylsilane mixtures
Soundararajan, Raman,Matteson, Donald S.
, p. 4157 - 4166 (2008/10/09)
Trialkylsilanes or dialkylsilanes react rapidly with boron trichloride in the absence of ethereal solvents or other nucleophiles to form unsolvated dichloroborane. If no substrate is present, dichloroborane disproportionates to trichloroborane and two geo
DERIVES MONO ET BICYCLIQUES DU BORE TETRACOORDONNE ET DES α-AMINODIACIDES: REACTIONS AVEC DIVERS NUCLEOPHILES
Garrigues, Bernard,Mulliez, Michel
, p. 19 - 24 (2007/10/02)
Water, methanol and isopropylamine react mono- and bi-cyclic boroxazolidones (2a and 3a) by attacking the boron atom and not the CO group, with formation of aminodiacid and tricoordinated boron compounds.The boron compounds undergo successive B-C cleavage