7335-09-3Relevant articles and documents
Formation of secondary or tertiary aliphatic amines in aqueous media
Marieta Simion, Alina,Arimura, Takashi,Miyazawa, Akira,Simion, Cristian,Surya Prakash,Olah, George A.,Tashiro, Masashi
scheme or table, p. 2859 - 2865 (2009/12/03)
Secondary and tertiary amines can be easily obtained from primary and secondary amines, respectively, in completely aqueous media, in the presence of a bicatalytic system formed of cheap commercial aluminum (Al) powder and 5% rhodium (Rh) or ruthenium (Ru) deposed on charcoal.
Cyclization of α,ω Aliphatic Diamines and Conversion of Primary Amines to Symmetrical Tertiary Amines by a Homogeneous Ruthenium Catalyst
Bui-The-Khai,Concilio, Carlo,Porzi, Gianni
, p. 1759 - 1760 (2007/10/02)
α,ω Aliphatic diamines were cyclized to heterocyclic amines by being heated at 180 deg C for 5 h with RuCl2(Ph3P)3 in diphenyl ether.Primary amines having an α-hydrogen atom are converted to symmetrical tertiary amines by being heated at 185 or 235 deg C for 8 h with RuCl3*3H2O and Ph3P in THF solution.