73607-12-2

Basic information

• Product Name: Benzene, 1-methoxy-4-[3,3,3-trifluoro-2-(trifluoromethyl)-1-propenyl]-
• CAS NO: 73607-12-2
• Molecular Formula: C11H8F6O
• Molecular Weight: 270.174
• Mol File: 73607-12-2.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Benzene, 1-methoxy-4-[3,3,3-trifluoro-2-(trifluoromethyl)-1-propenyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-methoxy-4-[3,3,3-trifluoro-2-(trifluoromethyl)-1-propenyl]-(73607-12-2)
• EPA Substance Registry System: Benzene, 1-methoxy-4-[3,3,3-trifluoro-2-(trifluoromethyl)-1-propenyl]-(73607-12-2)

Safety Data

• Hazardous Substances Data: 73607-12-2(Hazardous Substances Data)

Upstream product

• 77152-08-0 trifluoromethylcopper(I) 
• 82203-83-6 1-(p-methoxyphenyl)-3,3,3-trifluoropropyne 
• 680-15-9 2,2-difluoro-2-(fluorosulfonyl)acetate 
• 60512-57-4 1-(2,2-dibromovinyl)-4-methoxybenzene 
• 1652-80-8 2,2-dichloro-1,1,1,3,3,3-hexafluoro-propane 
• 123-11-5 4-methoxy-benzaldehyde 
• 791-50-4 2,2,4,4-Tetrakis(trifluoromethyl)-1,3-dithietane 

Relevant articles and documents

Domino Hydroboration/Trifluoromethylation of Alkynes Using Fluoroform-Derived [CuCF3]

A domino hydroboration/trifluoromethylation (formal hydrotrifluoromethylation) of alkynes using the fluoroform-derived [CuCF3] reagent is achieved. Synthetically useful (E)-alkenyl-CF3 building blocks and 1,1-bis(trifluoromethyl)-substituted alkenes can be prepared under ambient conditions in one pot/one step from alkynes. The ultimate source of CF3 is the inexpensive industrial waste fluoroform.

A New Synthesis of 1,1-Bis(trifluoromethyl)-Substituted Alkenes

1,1-Bis(trifluoromethyl)-substituted alkenes 6 are obtained by the reaction of aldehydes 5 with triphenylphosphine (4) and 2,2-dichlorohexafluoropropane (3) in modest to good yields.The alkenes 6 are not easily accessible by other routes.