7364-19-4

Basic information

• Product Name: 1-TERT-BUTYL-4-ETHYLBENZENE
• Synonyms: 1-TERT-BUTYL-4-ETHYLBENZENE;P-TERT-BUTYLETHYLBENZENE;1-(1,1-Dimethylethyl)-4-ethylbenzene;1-Ethyl-4-tert-butylbenzene
• CAS NO: 7364-19-4
• Molecular Formula: C₁₂H₁₈
• Molecular Weight: 162.27
• EINECS: 230-903-7
• Mol File: 7364-19-4.mol
• Article Data: 46

Chemical Properties

• Melting Point: -38.35°C
• Boiling Point: 212.1°C
• Flash Point: 75.9°C
• Appearance: /
• Density: 0.8617 (estimate)
• Vapor Pressure: 0.264mmHg at 25°C
• Refractive Index: 1.4933
• Stability: Stable. Combustible. Incompatible with strong oxidizing agents.
• CAS DataBase Reference: 1-TERT-BUTYL-4-ETHYLBENZENE(CAS DataBase Reference)
• NIST Chemistry Reference: 1-TERT-BUTYL-4-ETHYLBENZENE(7364-19-4)
• EPA Substance Registry System: 1-TERT-BUTYL-4-ETHYLBENZENE(7364-19-4)

Safety Data

• Hazardous Substances Data: 7364-19-4(Hazardous Substances Data)

Usage

General Description

1-Tert-butyl-4-ethylbenzene is a chemical compound that belongs to the class of organic compounds known as benzene and substituted derivatives. It is a colorless liquid with a faint odor, and is primarily used as a solvent in various industrial applications such as coatings, adhesives, and cleaning products. The chemical structure of 1-tert-butyl-4-ethylbenzene consists of a benzene ring substituted with a tert-butyl group and an ethyl group. It is known to have low toxicity and is relatively stable under normal conditions, but caution should still be taken when handling and storing this chemical to prevent potential health and environmental hazards.

InChI:InChI=1/C12H18/c1-5-10-6-8-11(9-7-10)12(2,3)4/h6-9H,5H2,1-4H3

Upstream product

• 78-83-1 2-methyl-propan-1-ol 
• 100-41-4 ethylbenzene 
• 507-19-7 t-butyl bromide 
• 78-77-3 Isobutyl bromide 
• 943-27-1 4'-t-butylacetophenone 
• 75-65-0 tert-butyl alcohol 
• 594-19-4 tert.-butyl lithium 
• 12203-31-5 (Ethylbenzene)tricarbonylchromium 
• 109-87-5 Dimethoxymethane 
• 98-51-1 4-tert-butyltoluene 
• 507-20-0 tertiary butyl chloride 
• 7705-08-0 iron(III) chloride 
• 253185-03-4 tert-butylbenzene 
• 74-85-1 ethene 

Downstream Products

• 57190-08-6 1-ethyl-2-bromo-4-tert-butyl-benzene 
• 107342-35-8 2-ethyl-5-tert-butyl-1,3-dinitro-benzene 
• 100862-89-3 1-(2-ethyl-4-tert-butyl-phenyl)-ethanone 
• 71028-33-6 3-Chlor-4-ethyl-1-t-butylbenzol 
• 1160718-16-0 C₁₂H₁₇NO₂ 
• 63452-65-3 5-tert-Butyl-2-ethyl-benzenesulfonamide 
• 81529-61-5 2-amino-4-(4′-tert-butylphenyl)thiazole 
• 30095-47-7 2-bromo-1-(4-(tert-butyl)phenyl)ethanone 
• 56108-12-4 4-tert-butylbenzamide 
• 1534-53-8 1-(tert-butyl)-4-(1-fluoroethyl)benzene 
• 1391853-99-8 (R)-1-phenyl-2,2,2-trichloroethyl (R)-1-(4-tert-butylphenyl)ethylcarbamate 
• 943-27-1 4'-t-butylacetophenone 
• 1231892-49-1 6-tert-butyl-2-(2-methyl-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl)isoindolin-1-one 
• 1361386-73-3 6-tert-butylisoindolin-1-one 

Relevant articles and documents

Chemoselective Hydrogenation of Olefins Using a Nanostructured Nickel Catalyst

The selective hydrogenation of functionalized olefins is of great importance in the chemical and pharmaceutical industry. Here, we report on a nanostructured nickel catalyst that enables the selective hydrogenation of purely aliphatic and functionalized olefins under mild conditions. The earth-abundant metal catalyst allows the selective hydrogenation of sterically protected olefins and further tolerates functional groups such as carbonyls, esters, ethers and nitriles. The characterization of our catalyst revealed the formation of surface oxidized metallic nickel nanoparticles stabilized by a N-doped carbon layer on the active carbon support.

Generalized Chemoselective Transfer Hydrogenation/Hydrodeuteration

A generalized, simple and efficient transfer hydrogenation of unsaturated bonds has been developed using HBPin and various proton reagents as hydrogen sources. The substrates, including alkenes, alkynes, aromatic heterocycles, aldehydes, ketones, imines, azo, nitro, epoxy and nitrile compounds, are all applied to this catalytic system. Various groups, which cannot survive under the Pd/C/H2 combination, are tolerated. The activity of the reactants was studied and the trends are as follows: styrene'diphenylmethanimine'benzaldehyde'azobenzene'nitrobenzene'quinoline'acetophenone'benzonitrile. Substrates bearing two or more different unsaturated bonds were also investigated and transfer hydrogenation occurred with excellent chemoselectivity. Nano-palladium catalyst in situ generated from Pd(OAc)2 and HBPin extremely improved the TH efficiency. Furthermore, chemoselective anti-Markovnikov hydrodeuteration of terminal aromatic olefins was achieved using D2O and HBPin via in situ HD generation and discrimination. (Figure presented.).

Direct Synthesis of Mono-α-arylated Ketones from Alcohols and Olefins via Ni-Catalyzed Oxidative Cross-Coupling

Controlled synthesis of α-monoarylated ketones is significant yet challenging due to the site-selectivity issues and nonproductive overarylation reactions. Herein, we reported the direct synthesis of α-arylated ketones enabled by Ni-catalyzed dehydrogenative cross-coupling reaction cascade between alcohols and olefins. The use of readily available and cost-effective alcohols and olefins provides a straightforward access to monoarylated ketones in good yields with exclusive selectivity without using any advanced synthetic intermediates.