73766-31-1

Basic information

• Product Name: (+)-(R)-(E-2-Octenyl)-p-tolyl-sulfoxid
• Synonyms: (+)-(R)-(E-2-Octenyl)-p-tolyl-sulfoxid
• CAS NO: 73766-31-1
• Molecular Weight: 250.405
• Mol File: 73766-31-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (+)-(R)-(E-2-Octenyl)-p-tolyl-sulfoxid(CAS DataBase Reference)
• NIST Chemistry Reference: (+)-(R)-(E-2-Octenyl)-p-tolyl-sulfoxid(73766-31-1)
• EPA Substance Registry System: (+)-(R)-(E-2-Octenyl)-p-tolyl-sulfoxid(73766-31-1)

Safety Data

• Hazardous Substances Data: 73766-31-1(Hazardous Substances Data)

Upstream product

• 109-72-8 n-butyllithium 
• 73766-34-4 (+)-(R)-(2-Acetoxy-3-butenyl)-p-tolyl-sulfoxid 
• 951133-73-6 (R)-(1,3-Butadienyl)-p-tolyl-sulfoxid 
• 61187-68-6 (R)-1-Octenyl-p-tolyl-sulfoxid 
• 111-71-7 heptanal 
• 1519-39-7 (R)-methyl p-tolyl sulfoxide 
• 73766-30-0 (R)-(p-Tolyl)-<2-(trimethylsilyloxy)octyl>-sulfoxid 
• 50921-35-2 (R)-(2-Hydroxyoctyl)-(p-tolyl)-sulfoxid 
• 63753-50-4 (R)-(2-Hydroxy-3-butenyl)-p-tolyl-sulfoxid 

Downstream Products

• 3391-86-4 1-octen-3-ol 

Relevant articles and documents

Stereoselective Synthesis of Alcohols, II Stereochemistry of the Sigmatropic Rearrangement of 3-Substituted 2-Alkenyl Sulfoxides

Rearrangement of the 3-E-substituted allyl sulfoxides 5 to the allyl alcohols 19 and 30 proceeds with low enantiomeric selectivity.In contrast, the 3-Z-substituted allyl sulfoxide 7b rearranged uniformly via the endo-transition state 26.