73794-49-7

Basic information

• Product Name: 1-ACETOXY-8-HYDROXY-1,4,4A,9A-TETRAHYDROANTHRAQUINONE)
• Synonyms: (1R,4aS,9aS)-8-hydroxy-9,10-dioxo-1,4,4a,9,9a,10-hexahydroanthracen-1-yl acetate
• CAS NO: 73794-49-7
• Molecular Formula: C₁₆H₁₄O₅
• Molecular Weight: 286.28
• Mol File: 73794-49-7.mol
• Article Data: 2

Chemical Properties

• Boiling Point: 495.4°C at 760 mmHg
• Flash Point: 187.5°C
• Appearance: /
• Density: 1.39g/cm³
• Vapor Pressure: 1.95E-10mmHg at 25°C
• Refractive Index: 1.622
• PKA: 6.85±0.40(Predicted)
• CAS DataBase Reference: 1-ACETOXY-8-HYDROXY-1,4,4A,9A-TETRAHYDROANTHRAQUINONE)(CAS DataBase Reference)
• NIST Chemistry Reference: 1-ACETOXY-8-HYDROXY-1,4,4A,9A-TETRAHYDROANTHRAQUINONE)(73794-49-7)
• EPA Substance Registry System: 1-ACETOXY-8-HYDROXY-1,4,4A,9A-TETRAHYDROANTHRAQUINONE)(73794-49-7)

Safety Data

• Hazardous Substances Data: 73794-49-7(Hazardous Substances Data)

Usage

InChI:InChI=1/C16H14O5/c1-8(17)21-12-7-3-5-10-14(12)16(20)13-9(15(10)19)4-2-6-11(13)18/h2-4,6-7,10,12,14,18H,5H2,1H3

Upstream product

• 1515-76-0 1-acetoxybuta-1,3-diene 
• 481-39-0 5-hydroxynaphtho-1,4-quinone 

Downstream Products

• 129-43-1 1-hydroxyanthraquinone 
• 82495-02-1 Acetic acid (1R,4aS,9R,9aR,10S)-8-benzyloxy-9,10-dihydroxy-10-methyl-1,4,4a,9,9a,10-hexahydro-anthracen-1-yl ester 
• 82495-03-2 (1S,4aR,9S,9aR,10R)-8-Benzyloxy-10-methyl-1,4,4a,9,9a,10-hexahydro-anthracene-1,9,10-triol 
• 82495-01-0 10β-Hydroxy-4β-acetoxy-5-benzyloxy-9-oxo-1,4,4aα,9,9aα,10-hexahydro-anthracen 
• 82495-00-9 4,10-dioxo-4aβ-chloro-5-(benzyloxy)-9β-hydroxy-9α-methyl-1,4,9,9aα,10-pentahydroanthracene 
• 82494-99-3 (4aR,9aR,10R)-8-Benzyloxy-10-hydroxy-10-methyl-4a,10-dihydro-4H,9aH-anthracene-1,9-dione 

Relevant articles and documents

The 'Mikami'-catalyst in enantioselective diels-alder reactions of juglone-based dienophiles with different 1-oxygenated dienes: An investigation on the substitution pattern dependent regioselectivity

A mechanistic study investigating the substitution pattern depending regioselectivity of enantioselective BINOL-Ti-catalyzed Diels-Alder reactions of juglone-based dienophiles with 1-oxygenated dienes is reported. The different influences of residues both on the diene as well as on the dienophiles are investigated giving a detailed picture of their role on the regioselectivity.