73842-46-3Relevant articles and documents
Enhanced Hydride Donation Achieved Molybdenum Catalyzed Direct N-Alkylation of Anilines or Nitroarenes with Alcohols: From Computational Design to Experiment
Huang, Ming,Huang, Yong-Liang,Ke, Zhuofeng,Lan, Xiao-Bing,Li, Weikang,Liu, Jiahao,Liu, Yan,Ye, Zongren,Zhao, Cunyuan
, p. 10377 - 10382 (2021/08/31)
An example of homogeneous Mo-catalyzed direct N-alkylation of anilines or nitroarenes with alcohols is presented. The DFT aimed design suggested the easily accessible bis-NHC-Mo(0) complex features a strong hydride-donating ability, achieving effective N-alkylation of anilines or challenging nitroarenes with alcohols. The enhanced hydride-donating strategy should be useful in designing highly active systems for borrowing hydrogen transformations.
A microwave-assisted SmI2-catalyzed direct N-alkylation of anilines with alcohols
Gour, Jitendra,Gatadi, Srikanth,Malasala, Satyaveni,Yaddanpudi, Madhavi Venkata,Nanduri, Srinivas
, p. 7488 - 7494 (2019/06/14)
A new protocol for the alkylation of aromatic amines has been described using alcohols in the presence of SmI2 as a catalyst with the generation of water as the sole byproduct. The reaction proceeds under MW conditions and selectively generates monoalkylated amines. This protocol features a broad substrate scope and good functional-group tolerance with moderate to high yields.
Application of carbon-supported ruthenium nanomaterial in preparation of N-alkyl aromatic amine compound
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Paragraph 0072, (2018/05/16)
The invention discloses preparation and a catalytic application of carbon material supported ruthenium nanoparticles. Specifically, the average particle size of the prepared ruthenium nanoparticles isabout 2.2 nm, and the ruthenium nanoparticles are unifo