73982-62-4

Basic information

• Product Name: (2R)-2-deoxy-2-deuterio-D-lyxo-hexose
• CAS NO: 73982-62-4
• Molecular Weight: 165.15
• Mol File: 73982-62-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (2R)-2-deoxy-2-deuterio-D-lyxo-hexose(CAS DataBase Reference)
• NIST Chemistry Reference: (2R)-2-deoxy-2-deuterio-D-lyxo-hexose(73982-62-4)
• EPA Substance Registry System: (2R)-2-deoxy-2-deuterio-D-lyxo-hexose(73982-62-4)

Safety Data

• Hazardous Substances Data: 73982-62-4(Hazardous Substances Data)

Upstream product

• 73982-61-3 (2R)-2-deoxy-2-deuterio-4,5-O-isopropylidene-D-lyxo-hexose dimethyl acetal 
• 73982-58-8 (2R)-3,6-di-O-acetyl-2-deoxy-2-deuterio-4,5-O-isopropylidene-D-lyxo-hexose diethyl dithioacetal 
• 73982-60-2 C₁₅H₂₅⁽²⁾HO₈ 
• 73982-54-4 2-deoxy-4,5-O-isopropylidene-D-lyxo-hex-1-enose diethyl dithioacetal 
• 73982-56-6 (2R)-2-deoxy-2-deuterio-4,5-O-isopropylidene-D-lyxo-hexose diethyl dithioacetal 
• 6207-30-3 2,3:4,5-di-O-isopropylidene-D-galactose diethyl dithioacetal 

Relevant articles and documents

2-DEOXY-D-arabino-HEXOSE, 2-DEOXY-D-lyxo-HEXOSE, AND THEIR (2R)-2-DEUTERIO ANALOGS

A general method for the synthesis of 2-deoxyhexoses is described. 2-Deoxy-D-arabino-hexose and 2-deoxy-D-lyxo-hexose were prepared from D-glucose and D-galactose, respectively, by a route involving reduction of the respective 4,5-O-isopropylidene ketene diethyl dithioacetals with lithium aluminum hydride, followed by removal of the protecting groups.In agreement with the results of earlier studies with ketene dithioacetals of pentose analogs, reduction of the hexose ketene dithioacetals was found to occur both regio- and stereo-specifically.Reduction with lithium aluminum deuteride gave the (2R)-2-deoxy-2-deuterio-hexoses exclusively.