74063-89-1

Basic information

• Product Name: ethyl 2-(trimethylsilyloxy)cyclohex-1-enecarboxylate
• Synonyms: ethyl 2-(trimethylsilyloxy)cyclohex-1-enecarboxylate
• CAS NO: 74063-89-1
• Molecular Weight: 242.39
• Mol File: 74063-89-1.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: ethyl 2-(trimethylsilyloxy)cyclohex-1-enecarboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: ethyl 2-(trimethylsilyloxy)cyclohex-1-enecarboxylate(74063-89-1)
• EPA Substance Registry System: ethyl 2-(trimethylsilyloxy)cyclohex-1-enecarboxylate(74063-89-1)

Safety Data

• Hazardous Substances Data: 74063-89-1(Hazardous Substances Data)

Upstream product

• 10416-59-8 N,O-bis-(trimethylsilyl)-acetamide 
• 1655-07-8 ethyl 2-oxocyclohexane carboxylate 
• 27607-77-8 trimethylsilyl trifluoromethanesulfonate 
• 75-77-4 chloro-trimethyl-silane 

Downstream Products

• 685139-80-4 ethyl (1S)-2-oxo-1-[(2E)-3-phenylprop-2-en-1-yl]cyclohexanecarboxylate 
• 1328887-11-1 ethyl 7-(benzylamino)-2-(hydroxyimino)-7-oxoheptanoate 
• 1328887-10-0 ethyl 2-(hydroxyimino)-7-oxo-7-(phenylamino)heptanoate 
• 1194050-01-5 methyl 5-((1-(ethoxycarbonyl)-2-oxocyclohexyl)methyl)-3,4-dihydropyridine-1(2H)-carboxylate 
• 7251-30-1 (1-ethoxycarbonyl-2-oxo-cyclohexyl)-acetic acid ethyl ester 
• 275383-45-4 6-[1-Ethoxy-1-trimethylsilanyloxy-meth-(E)-ylidene]-1-trimethylsilanyloxy-cyclohexene 

Relevant articles and documents

Metal nitrite: A powerful oxidizing reagent

An efficient and simple source of nitroso reagents and their oxidation reactions are described. The combination of a Lewis acid and a metal nitrite was applied to the oxidation of silyl enol ethers. Amino acid and peptide derivatives were easily accessed through in situ C-C bond cleavage of fully substituted silyl enol ethers upon oxidation.

Regioselective synthesis and acylation of cyclic bis-(trimethylsiloxy)- 1,3-dienes - New and versatile 1,3-dianion synthons

Cyclohexanone-derived bis-(trimethylsiloxy)-1,3-dienes were regioselectively prepared by the use of different silylating systems. These dienes represent new and versatile 1,3-dianion synthons in Lewis-acid catalyzed acylation reactions.

An Annelation Approach to the Synthesis of Eudesmane and Elemane Sesquiterpene Lactones. Total Synthesis of dl-Dihydrocallitrisin, dl-7,8-Epialantolactone, dl-7,8-Epiisoalantolactone, and dl-Atractylon

An annelation approach to the synthesis of eudesmane sesquiterpenes is described.The 1,6-annelation reagent α-carbomethoxy-β-methyl-γ-methylidene-Δα,β-butenolide (1) is used to construct the linear tricyclic lactone 2,5,6,7,8,8a,9,9aβ-octahydro-8aβ-methyl-2-oxonaphthofuran-3-carboxylic acid methyl ester (2).The conversion of 2 to dl-dihydrocallitrisin (3), dl-7,8-epialantolactone (4), dl-7,8-epiisoalantolactone (5), and dl-atractylon (6) is detailed.Studies directed toward synthesis of the elemane sesquiterpene lactones vernomenin and vernolepin also are presented.