74097-67-9

Basic information

• Product Name: (+/-)-(4S,5S)-4,5-dihydro-5-methyl-3,5-diphenyl-1-tosyl-1H-pyrazol-4-ol
• Synonyms: (+/-)-(4S,5S)-4,5-dihydro-5-methyl-3,5-diphenyl-1-tosyl-1H-pyrazol-4-ol
• CAS NO: 74097-67-9
• Molecular Weight: 406.505
• Mol File: 74097-67-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (+/-)-(4S,5S)-4,5-dihydro-5-methyl-3,5-diphenyl-1-tosyl-1H-pyrazol-4-ol(CAS DataBase Reference)
• NIST Chemistry Reference: (+/-)-(4S,5S)-4,5-dihydro-5-methyl-3,5-diphenyl-1-tosyl-1H-pyrazol-4-ol(74097-67-9)
• EPA Substance Registry System: (+/-)-(4S,5S)-4,5-dihydro-5-methyl-3,5-diphenyl-1-tosyl-1H-pyrazol-4-ol(74097-67-9)

Safety Data

• Hazardous Substances Data: 74097-67-9(Hazardous Substances Data)

Upstream product

• 19804-64-9 trans-(3-methyl-3-phenyloxiran-2-yl)(phenyl)methanone 
• 98-86-2 acetophenone 
• 6397-70-2 3-hydroxy-1,3-diphenylbutan-1-one 
• 54435-79-9 (E)-1,3-diphenyl-3-methyl-2-propen-1-one 

Downstream Products

• 74097-98-6 (3S,5R)-3,5-Dimethyl-3,5-diphenyl-3,5-dihydro-pyrazol-4-one 
• 74097-84-0 (3S,4S,5R)-3,5-Dimethyl-3,5-diphenyl-4,5-dihydro-3H-pyrazol-4-ol 
• 74097-91-9 5-Methyl-3,5-diphenyl-1-(toluene-4-sulfonyl)-1,5-dihydro-pyrazol-4-one 

Relevant articles and documents

Stereoselective synthesis of 3,5-dialkyl-3,5-dihydro-3,5-diphenyl-4H- pyrazol-4-ones

We report stereoselective five-step syntheses of cis-3-ethyl-3,5-dihydro-3, 5-diphenyl-5-methyl-4H-pyrazol-4-one (cis-1b) and trans-3,5-diethyl-3,5-dihydro- 3,5-diphenyl-4H-pyrazol-4-one (trans-1c). The key synthon was 1,3-diphenylpent-2-en-1-one (5b) synthesized in a new one-pot crossed aldol/dehydration reaction of acetophenone with propiophenone using titanium(IV) chloride/tributylamine, followed by treatment with methanesulfonyl chloride and triethylamine. Georg Thieme Verlag Stuttgart.