74128-90-8

Basic information

• Product Name: 2,2,2',2'-Tetrachlor-1,1'-diphenyl-2,2'-trithiobis(ethanon)
• Synonyms: 2,2,2',2'-Tetrachlor-1,1'-diphenyl-2,2'-trithiobis(ethanon)
• CAS NO: 74128-90-8
• Molecular Weight: 472.264
• Mol File: 74128-90-8.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 2,2,2',2'-Tetrachlor-1,1'-diphenyl-2,2'-trithiobis(ethanon)(CAS DataBase Reference)
• NIST Chemistry Reference: 2,2,2',2'-Tetrachlor-1,1'-diphenyl-2,2'-trithiobis(ethanon)(74128-90-8)
• EPA Substance Registry System: 2,2,2',2'-Tetrachlor-1,1'-diphenyl-2,2'-trithiobis(ethanon)(74128-90-8)

Safety Data

• Hazardous Substances Data: 74128-90-8(Hazardous Substances Data)

Upstream product

• 98-86-2 acetophenone 

Downstream Products

• 98-88-4 benzoyl chloride 
• 594-42-3 chlorothio-trichloro-methane 
• 87342-60-7 N,N-dimethyl-2-phenyl-2-thioxothiacetamide 
• 40531-91-7 N,N-dimethyl-2-oxo-2-phenylethanethioamide 

Relevant articles and documents

One-Step Conversion of Methyl Ketones to Acyl Chlorides

Treatment of aromatic and heteroaromatic methyl ketones with sulfur monochloride and catalytic amounts of pyridine in refluxing chlorobenzene leads to the formation of acyl chlorides. Both electron-rich and electron-poor aryl methyl ketones can be used as starting materials. The resulting C1-byproduct depends on the precise reaction conditions chosen.

α-Oxo- and α-Thioxothioamides from Methyl Ketones

Mixtures of α-(chloro)sulfenyl chlorides 5 and trisulfides 6 are obtained from the reaction of thionyl chloride with methyl ketones in the presence of pyridine.From these mixtures as well as from the pure trisulfides 6, with amines the α-oxothioamides 1-4