741681-54-9Relevant articles and documents
Site- and Regioselective Monoalkenylation of Pyrroles with Alkynes via Cp?CoIII Catalysis
Tanaka, Ryo,Ikemoto, Hideya,Kanai, Motomu,Yoshino, Tatsuhiko,Matsunaga, Shigeki
supporting information, p. 5732 - 5735 (2016/11/17)
A site-, regio-, syn-, and monoselective alkenylation of dimethylcarbamoyl-protected pyrroles proceeded using a catalytic amount of [Cp?Co(CH3CN)3](SbF6)2 and KOAc. A variety of internal alkynes with several fun
Regioselective C2 oxidative olefination of indoles and pyrroles through cationic rhodium(III)-Catalyzed C-H bond activation
Li, Bin,Ma, Jianfeng,Xie, Weijia,Song, Haibin,Xu, Shansheng,Wang, Baiquan
supporting information, p. 11863 - 11868 (2013/09/23)
Be economic with your atoms! An efficient Rh-catalyzed oxidative olefination of indoles and pyrroles with broad substrate scope and tolerance is reported (see scheme). The catalytic reaction proceeds with excellent regio- and stereoselectivity. The directing group N,N-dimethylcarbamoyl was crucial for the reaction and could be removed easily. Copyright