7429-08-5

Basic information

• Product Name: 1-benzoyloxy-1-methyl-1-phenylethane
• Synonyms: 1-benzoyloxy-1-methyl-1-phenylethane
• CAS NO: 7429-08-5
• Molecular Weight: 240.302
• Mol File: 7429-08-5.mol
• Article Data: 9

Chemical Properties

• CAS DataBase Reference: 1-benzoyloxy-1-methyl-1-phenylethane(CAS DataBase Reference)
• NIST Chemistry Reference: 1-benzoyloxy-1-methyl-1-phenylethane(7429-08-5)
• EPA Substance Registry System: 1-benzoyloxy-1-methyl-1-phenylethane(7429-08-5)

Safety Data

• Hazardous Substances Data: 7429-08-5(Hazardous Substances Data)

Upstream product

• 80-15-9 Cumene hydroperoxide 
• 140-29-4 phenylacetonitrile 
• 617-94-7 1-methyl-1-phenylethyl alcohol 
• 98-88-4 benzoyl chloride 
• 98-82-8 Isopropylbenzene 
• 108-88-3 toluene 
• 65-85-0 benzoic acid 
• 93-58-3 benzoic acid methyl ester 
• 74-88-4 methyl iodide 
• 612058-36-3 (1-methyl-1-phenylethoxy)di(phenyl)phosphine 
• 614-45-9 tert-Butyl peroxybenzoate 
• 108-90-7 chlorobenzene 
• 67-64-1 acetone 
• 94-36-0 dibenzoyl peroxide 

Relevant articles and documents

Silver/manganese dioxide nanorod catalyzed hydrogen-borrowing reactions and tert-butyl ester synthesis

Silver/manganese dioxide (Ag@MnO2) nanorods are synthesized and characterized by scanning electron microscopy, transmission electron microscopy, energy dispersive X-ray spectroscopy, X-ray powder diffraction, and X-ray photoelectron spectroscopy. It was discovered that Ag@MnO2 nanorods can realize hydrogen-borrowing reactions in high yields and are also effective for the synthesis of tert-butyl esters from aryl cyanides and tert-butyl hydroperoxide in a short period of time. Mechanistic experiments revealed that this catalytic system acts as a Lewis acid in hydrogen-borrowing reactions, while the synthesis of tert-butyl esters occurs through a radical pathway. This is the first report on the excellent catalytic activity of Ag@MnO2 nanorods as a catalyst.

Efficient O-Acylation of Alcohols and Phenol Using Cp2TiCl as a Reaction Promoter

A method has been developed for the conversion of primary, secondary, and tertiary alcohols, and phenol, into the corresponding esters at room temperature. The method uses a titanium(III) species generated from a substoichiometric amount of titanocene dichloride together with manganese(0) as a reductant, as well as methylene diiodide. It involves a transesterification from an ethyl ester, or a reaction with an acyl chloride. A radical mechanism is proposed for these transformations.

A metal-free oxidative esterification of the benzyl C-H bond

An efficient metal-free oxidative esterification of benzyl C-H bonds was developed. Using tetrabutylammonium iodide as catalyst and tert-butyl hydroperoxide as co-oxidant, benzylic substrates could react smoothly with various carboxylic acids to give the esters with good to excellent yields. The method was also suitable for the O-protection of N-Boc amino acids. The reaction mechanism was primarily investigated and a radical process was proposed. Copyright