74376-28-6Relevant articles and documents
Formation of 2-Imino-1,3-oxathioles and 2(3H)-Oxazolethione by the Rhodium(II) Acetate-Catalyzed Reaction of α-Diazocarbonyl Compounds with Isothiocyanates
Ibata, Toshikazu,Nakano, Hirofumi
, p. 3088 - 3093 (2007/10/02)
The rhodium(II) acetate-catalyzed reaction of various α-diazocarbonyl compounds with alkyl, phenyl, and benzoyl isothiocyanates gave 2-imino-1,3-oxathioles in good yields. 2(3H)-Oxazolethione was obtained as a byproduct only in the reaction of diazodimedo