74457-44-6

Basic information

• Product Name: methyl 4-keto-2-phenylpentanoate
• Synonyms: methyl 4-keto-2-phenylpentanoate
• CAS NO: 74457-44-6
• Molecular Weight: 206.241
• Mol File: 74457-44-6.mol
• Article Data: 14

Chemical Properties

• CAS DataBase Reference: methyl 4-keto-2-phenylpentanoate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 4-keto-2-phenylpentanoate(74457-44-6)
• EPA Substance Registry System: methyl 4-keto-2-phenylpentanoate(74457-44-6)

Safety Data

• Hazardous Substances Data: 74457-44-6(Hazardous Substances Data)

Upstream product

• 186581-53-3 diazomethane 
• 4439-87-6 2-phenyllevulinic acid 
• 1729-26-6 (±)-5-(iodomethyl)-3-phenyldihydrofuran-2(3H)-one 
• 74-88-4 methyl iodide 
• 624-48-6 dimethyl cis-but-2-ene-1,4-dioate 
• 98-13-5 Phenyltrichlorosilane 
• 104637-14-1 (+)-(R)-1,3-diphenyl-1-hexen-5-one 
• 13049-41-7 1,1-dimethoxy-2-phenylethene 
• 103-82-2 phenylacetic acid 
• 101-41-7 benzeneacetic acid methyl ester 
• 14815-73-7 methyl allylphenylacetate 
• 124-38-9 carbon dioxide 
• 122-57-6 1-Phenylbut-1-en-3-one 
• 139616-15-2 C₁₂H₁₇O₅P 

Downstream Products

• 148493-20-3 (R)-2-phenyl-4-oxopentanoic acid 
• 4439-87-6 2-phenyllevulinic acid 

Relevant articles and documents

Silicone as an organosilicon reagent 2. Rhodium-catalyzed conjugate addition of the silicone reagent to α,β-unsaturated carbonyl compounds

The reaction of poly(phenylmethylsiloxane) with α,β-unsaturated carbonyl compounds in the presence of aqueous K2CO3 and 3 mol% of [Rh(OH)(cod)]2 gives 1,4-conjugate addition product in good yields. Arylchlorosilanes also u

Photochemical Wittig Reaction of Quasi-phosphonium Ylides

α-(Methoxycarbonyl)benzylidene quasi-phosphonium ylides, which are unreactive towards most carbonyl compounds, are found to undergo the Wittig reaction upon irradiation; irradiation with acyclic carbonyl compounds, e.g. benzaldehydes and acetophenones, af