7465-10-3Relevant articles and documents
SUR LA REACTION DE PREFORMATSKY. PREPARATION ET REACTIVITE DE L'ORGANOZINCIQUE ISSU DU SEL BROMOZINCIQUE DE L'ACIDE γ-BROMOCROTONIQUE
Bellassoued, M.,Habbachi, F.,Gaudemar, M.
, p. 1299 - 1306 (1985)
The condensation of aldehydes and ketones with the bromozinc salt derived from γ-bromocrotonic acid, in the presence of zinc, yield to the "linear" and "branched" unsaturated hydroxyacids.These latters, which represent the kinetic products of the reaction, equilibrate at the alcoholate state to give, after hydrolysis, the "linear" compounds.