74882-32-9

Basic information

• Product Name: 3-Pentanone, 1,5-bis(4-methoxyphenyl)-
• CAS NO: 74882-32-9
• Molecular Formula: C19H22O3
• Molecular Weight: 298.382
• Mol File: 74882-32-9.mol
• Article Data: 15

Chemical Properties

• CAS DataBase Reference: 3-Pentanone, 1,5-bis(4-methoxyphenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Pentanone, 1,5-bis(4-methoxyphenyl)-(74882-32-9)
• EPA Substance Registry System: 3-Pentanone, 1,5-bis(4-methoxyphenyl)-(74882-32-9)

Safety Data

• Hazardous Substances Data: 74882-32-9(Hazardous Substances Data)

Upstream product

• 2051-07-2 1,5-bis-(4-methoxyphenyl)-1,4-pentadien-3-one 
• 637-69-4 4-Methoxystyrene 
• 143-33-9 sodium cyanide 
• 67-64-1 acetone 
• 105-13-5 4-Methoxybenzyl alcohol 
• 41973-35-7 1.5-Di-(4-methoxyphenyl)-3-hydroxypentane 
• 123-11-5 4-methoxy-benzaldehyde 
• 2051-07-2 bis(p-methoxybenzylidene)acetone 
• 100-46-9 benzylamine 
• 67-56-1 methanol 

Downstream Products

• 1374458-50-0 3,3-dihydroperoxy-1,5-bis(4'-methoxyphenyl)pentane 
• 4877-10-5 1,5-bis(4-methoxyphenyl)pentane 
• 93652-23-4 1,5-bis(4-hydroxyphenyl)-3-pentanone 
• 13612-53-8 β,β-Di-<β-(p-methoxy-phenyl)-aethyl>-acrylsaeure-methylester 
• 137569-07-4 C₄₅H₅₀O₅ 
• 137794-36-6 2,6-bis(4'-methoxybenzyl)-4-nitrophenylacetate 
• 199990-69-7 4-[5-Ethyl-4-(3-{4-(4-methoxy-phenyl)-2-[2-(4-methoxy-phenyl)-ethyl]-butylamino}-benzoyl)-1-methyl-1H-pyrrol-2-yl]-butyric acid ethyl ester 
• 137794-33-3 2,6-bis(4'-methoxybenzyl)-4-nitrophenol 
• 13579-12-9 <1,5-Di-(p-methoxyphenyl)-3-pentyliden>-cyanacetamid 
• 13612-52-7 β-Hydroxy-β,β-di-<β'-(p-methoxy-phenyl)-aethyl>-propionsaeure-methylester 

Relevant articles and documents

Highly productive α-alkylation of ketones with alcohols mediated by an Ir-oxalamidato/solid base catalyst system

An Ir-oxalamidato complex in combination with a solid base (e.g., magnesium aluminometasilicate/Ca(OH)2) significantly improved the catalyst productivity in α-alkylation of methyl ketones with primary alcohols. Optimization through systematic variation of the oxalamidato ligand led to a practical turnover number (TON) of 10 000.40 000.

Tandem hydrogenation and condensation of fluorinated α,β-unsaturated ketones with primary amines, catalyzed by nickel

A simple homogeneous catalytic system based on nickel phosphine complexes has been developed for the transfer hydrogenation and condensation of α,β-unsaturated ketones to yield saturated ones and saturated imines using primary amines as hydrogen donors. Thus, a wide range of fluorinated 1,5-diaryl-1,4-pentadiene-3-ones were allowed to react with substituted benzylamines in the presence of [(dippe)Ni(μ-H)]2 (dippe = 1,2-bis-(diisopropylphosphino)-ethane) using ethanol as a solvent at 180 °C to give the corresponding saturated carbonyl compounds; here hydrogenation of the CC bond was preferred over the CO bond. Under the same reaction conditions but using an excess of benzylamine, a tandem process is then favoured, starting also with the reduction of the CC bond followed by a nucleophilic addition of the primary amine to yield valuable saturated imines with good to excellent yields (62%-91%).

Use of Saccharomyces cerevisiae yeasts in the chemoselective bioreduction of (1E,4E)-1,5-bis(4-methoxyphenyl)-1,4-pentadien-3-one in biphasic system

This work describes the chemoselective bioreduction of (1E,4E)-1,5-bis(4- methoxyphenyl)- 1,4-pentadien-3-one (1) mediated by baker's yeast (BY, Saccharomyces cerevisiae cells) in an aqueous/organic solvent biphasic system. The biotransformation of this c