7510-54-5

Basic information

• Product Name: benzene-1,3,5-triyl tribenzoate
• Synonyms: 1,3,5-benzenetriol, tribenzoate
• CAS NO: 7510-54-5
• Molecular Formula: C₂₇H₁₈O₆
• Molecular Weight: 438.4282
• Mol File: 7510-54-5.mol
• Article Data: 4

Chemical Properties

• Boiling Point: 608.7°C at 760 mmHg
• Flash Point: 262.6°C
• Density: 1.29g/cm³
• Vapor Pressure: 9.26E-15mmHg at 25°C
• Refractive Index: 1.632
• CAS DataBase Reference: benzene-1,3,5-triyl tribenzoate(CAS DataBase Reference)
• NIST Chemistry Reference: benzene-1,3,5-triyl tribenzoate(7510-54-5)
• EPA Substance Registry System: benzene-1,3,5-triyl tribenzoate(7510-54-5)

Safety Data

• Hazardous Substances Data: 7510-54-5(Hazardous Substances Data)

Upstream product

• 108-73-6 3,5-dihydroxyphenol 
• 93-97-0 benzoic acid anhydride 
• 65-85-0 benzoic acid 
• 98-88-4 benzoyl chloride 
• 85909-02-0 N-benzyl-N-(tert-butoxycarbonyl)-benzamide 
• 100-39-0 benzyl bromide 

Downstream Products

• 885481-25-4 acetic acid 10-(3,5-dihydroxy-phenoxymethyl)-anthracen-9-ylmethyl ester 
• 885481-24-3 C₃₈H₂₈O₇ 
• 1818-24-2 2,4,6-tribenzoyl-phloroglucinol 

Relevant articles and documents

Hydrogen-bond-assisted transition-metal-free catalytic transformation of amides to esters

The amide C-N cleavage has drawn a broad interest in synthetic chemistry, biological process and pharmaceutical industry. Transition-metal, luxury ligand or excess base were always vital to the transformation. Here, we developed a transition-metal-free hydrogen-bond-assisted esterification of amides with only catalytic amount of base. The proposed crucial role of hydrogen bonding for assisting esterification was supported by control experiments, density functional theory (DFT) calculations and kinetic studies. Besides broad substrate scopes and excellent functional groups tolerance, this base-catalyzed protocol complements the conventional transition-metal-catalyzed esterification of amides and provides a new pathway to catalytic cleavage of amide C-N bonds for organic synthesis and pharmaceutical industry. [Figure not available: see fulltext.]

Construction of divergent anthracene arrays within dendritic frameworks

This publication presents simple methodologies for construction of divergent anthracene arrays either within structural interior or at peripheral positions of dendritic frameworks. The synthetic approaches employed multiple coupling reactions between two types of 10-functionalized 9-anthryl chlorides and two types of polyphenolic linkers, resulting in four types of dendritic architectures. Successful implementation of the syntheses was confirmed by a range of spectroscopies along with elemental analyses and size exclusion chromatography studies. The resulting dendritic molecules showed a range of solubilities in chloroform fairly affected by the dendritic backbone structures. Fluorescence spectroscopic experiments of the multichromophoric dendritic systems indicated pronounced energy delocalization functionalities via an energy migration within the branched molecular frameworks as expressed in reduced fluorescence quantum yields and complex emission decay profiles.