75154-95-9

Basic information

• Product Name: (1R,6Z)-1-Hydroxy-9,10-secocholesta-5⁽¹⁰⁾,6,8-⁽¹⁴⁾-triene
• Synonyms: (1R,6Z)-1-Hydroxy-9,10-secocholesta-5⁽¹⁰⁾,6,8-⁽¹⁴⁾-triene
• CAS NO: 75154-95-9
• Molecular Weight: 384.646
• Mol File: 75154-95-9.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (1R,6Z)-1-Hydroxy-9,10-secocholesta-5⁽¹⁰⁾,6,8-⁽¹⁴⁾-triene(CAS DataBase Reference)
• NIST Chemistry Reference: (1R,6Z)-1-Hydroxy-9,10-secocholesta-5⁽¹⁰⁾,6,8-⁽¹⁴⁾-triene(75154-95-9)
• EPA Substance Registry System: (1R,6Z)-1-Hydroxy-9,10-secocholesta-5⁽¹⁰⁾,6,8-⁽¹⁴⁾-triene(75154-95-9)

Safety Data

• Hazardous Substances Data: 75154-95-9(Hazardous Substances Data)

Upstream product

• 67619-75-4 de-A,B-8ξ-ethynyl-14-epicholestan-8ξ-ol 
• 89998-58-3 1-(tert-butyldimethylsiloxy)-3-ethynyl-2-methylcyclohex-2-ene 
• 89998-63-0 (1R,3aS,7aR)-4-[3-(tert-Butyl-dimethyl-silanyloxy)-2-methyl-cyclohex-1-enylethynyl]-1-((R)-1,5-dimethyl-hexyl)-7a-methyl-octahydro-inden-4-ol 
• 89998-61-8 14-epi-9,10-secocholesta-5⁽¹⁰⁾,8-dien-6-yn-1-one 
• 89998-59-4 de-A,B-8-ethynyl-14-epicholest-8-ene 
• 89998-57-2 3-ethynyl-2-methylcyclohex-2-en-1-ol 
• 89998-56-1 3-ethynyl-2-methylcyclohex-2-en-1-one 
• 75197-02-3 (1R,3aS,7aR)-1-[(R)-1,5-dimethylhexyl]-7a-methyloctahydroinden-4-one 
• 74398-26-8 (6R)-9,10-secocholesta-5⁽¹⁰⁾,6,7-triene-1-one 
• 67632-48-8 (1R,6R)-1-hydroxy-9,10-secocholesta-5⁽¹⁰⁾,6,7-triene 
• 67619-74-3 (1R,10S)-(5Z,7Z)-1-hydroxy-9,10-secocholesta-5,7,14-triene 
• 74398-25-7 de-A,B-8α-ethynyl-8β-cholestanol benzoate 
• 67619-70-9 2-methyl-3-iodocyclohex-2-en-1-ol 
• 67670-81-9 (1R,10R)-(5Z,7Z)-1-hydroxy-9,10-secocholesta-5,7,14-triene 

Downstream Products

• 67670-81-9 (1R,10R)-(5Z,7Z)-1-hydroxy-9,10-secocholesta-5,7,14-triene 
• 67619-74-3 (1R,10S)-(5Z,7Z)-1-hydroxy-9,10-secocholesta-5,7,14-triene 

Relevant articles and documents

Thermal -Sigmatropic Hydrogen Shifts: Stereochemistry, Kinetics, Isotope Effects, and ?-Facial Selectivity

The antarafacial stereochemistry of the thermal -sigmatropic hydrogen shift has been demonstrated.The substrates studied include the epimeric cis-isotachysterol analogues 1 and 4 and their stereospecifically 15α-deuterium-labelled derivatives 7 and 1

Studies on Vitamin D (Calciferol) and Its Analogues. 18. The Vinylallene Approach to the 1-Hydroxyvitamin D System. New Sigmatropic Reactions in the Vitamin D Series

The thermally induced -sigmatropic hydrogen shift of the diastereomeric vitamin D type vinylallenols 6a (1R,6R), 6b (1R,6S), 7a (1S,6S) and vinylallenols 5a (6R) and 5b (6S) were studied.The 1S,6S (7b) and 1R,6R(6a) alcohols afforded ca. 60percent yi