75243-71-9Relevant articles and documents
Dienyl homoallyl alcohols via palladium catalyzed ene-type reaction of aldehydes with 1,3-dienes
Fukushima, Masahiro,Takushima, Daiki,Kimura, Masanari
supporting information; experimental part, p. 16346 - 16348 (2011/02/22)
The combination of Pd catalyst and Xantphos ligand in the presence of Et3B nicely promotes the allylation of aldehydes with conjugated dienes to provide dienyl homoallyl alcohols in excellent yields. The reaction occurs selectively at the C-C double bond bearing higher electron density.
REGIOSPECIFIC CYCLOADDITION REACTIONS USING FUNCTIONALIZED ISOPRENYLSILANE AND RELATED COMPOUNDS
Hosomi, Akira,Sakata, Yasuyuki,Sakurai, Hideki
, p. 5175 - 5178 (2007/10/02)
1-Alkoxy-3-trimethylsilylmethyl- and 1-alkoxy-3-trimethylsilyl-l,3-butadienes (1) were newly prepared.The cycloaddition reactions of 1 with various dienophiles including heterodienophiles were found to proceed very smoothly in a perfectly regiospecific mo