75295-62-4Relevant articles and documents
THE SYNTHESIS AND REACTIONS OF ortho BROMOPHENYLLITHIUM
Chen, Loomis S.,Chen, Grace J.,Tamborski, Christ
, p. 283 - 292 (2007/10/02)
Experimental conditions have now been developed whereby o-bromophenyl-lithium(II) may be prepared in excellent yields and used as an organometallic intermediate for the synthesis of a variety of ortho bromo substituted phenyl compounds (o-BrC6H4X).The thermal stability, decomposition products and reactions of II were studied.Reactions between II and a variety of substrates, e.g., CO2, dimethylformamide, fluorinated esters, hexafluorobenzene, and organosilicon chlorides were examined.