75328-57-3

Basic information

• Product Name: Bicyclo[3.1.1]heptane, 1-methoxy-
• CAS NO: 75328-57-3
• Molecular Formula: C8H14O
• Molecular Weight: 126.199
• Mol File: 75328-57-3.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Bicyclo[3.1.1]heptane, 1-methoxy-(CAS DataBase Reference)
• NIST Chemistry Reference: Bicyclo[3.1.1]heptane, 1-methoxy-(75328-57-3)
• EPA Substance Registry System: Bicyclo[3.1.1]heptane, 1-methoxy-(75328-57-3)

Safety Data

• Hazardous Substances Data: 75328-57-3(Hazardous Substances Data)

Upstream product

• 67-56-1 methanol 
• 65513-21-5 tricyclo[3.1.1.0^1,5]heptane 
• 111830-40-1 1-bromobicyclo<3.1.1.>heptane 

Relevant articles and documents

Enhanced Solvolytic Reactivity of 1-Bromobicycloheptane: Intermediacy of a Stabilised Bridgehead Carbenium Ion

1-Bromobicycloheptane displays greater solvolytic reactivity than t-butyl bromide and produces a bridgehead carbenium ion which appears to be stabilised by transannular orbital interactions.

THROUGH-SPACE EFFECTS OF SUBSTITUENTS ON THE STABILITY OF THE 1-BICYCLOHEPTYL CATION.

γ-Substituents are shown to have a dramatic effect on the stabilisation of the cationic transition state for solvolysis of 5-substituted bicycloheptyl bromides.