75337-05-2

Basic information

• Product Name: 2-Cyclohexen-1-one, 4-methyl-, (R)-
• CAS NO: 75337-05-2
• Molecular Formula: C7H10O
• Molecular Weight: 110.156
• Mol File: 75337-05-2.mol
• Article Data: 50

Chemical Properties

• CAS DataBase Reference: 2-Cyclohexen-1-one, 4-methyl-, (R)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Cyclohexen-1-one, 4-methyl-, (R)-(75337-05-2)
• EPA Substance Registry System: 2-Cyclohexen-1-one, 4-methyl-, (R)-(75337-05-2)

Safety Data

• Hazardous Substances Data: 75337-05-2(Hazardous Substances Data)

Upstream product

• 78-85-3 2-methylpropenal 
• 1007476-32-5 sodium ethyl acetylacetate enolate 
• 64229-82-9 1-chloro-5-methyl-2-oxo-cyclohexanecarboxylic acid ethyl ester 
• 127-09-3 sodium acetate 
• 64-19-7 acetic acid 
• 81841-91-0 8-Benzenesulfonyl-8-methyl-1,4-dioxa-spiro[4.5]dec-6-ene 
• 38671-78-2 4-methyl-1-(trimethylsilyloxy)-1-cyclohexene 
• 7664-93-9 sulfuric acid 
• 20023-36-3 2,5-dihydro-4-methylanisole 
• 5259-65-4 4-methyl-3-cyclohexen-1-one 
• 3375-31-3 palladium diacetate 
• 589-91-3 p-methylcyclohexanol 
• 13368-65-5 (3R)-3-methylcyclohexanone 
• 82297-09-4 4-Methyl-1-morpholin-4-yl-cyclohex-3-enecarbonitrile 

Downstream Products

• 89088-84-6 trans-3,4-dimethyl-1-(trimethylsiloxy)cyclohexene 
• 109314-82-1 ((1S,2R)-2-Methyl-5-oxo-cyclohexyl)-dithioacetic acid methyl ester 
• 109314-82-1 ((1S,2S)-2-Methyl-5-oxo-cyclohexyl)-dithioacetic acid methyl ester 
• 83333-96-4 1-phenyl-cis-4-methyl-2-cyclohexen-1-ol 
• 83333-94-2 1-phenyl-trans-4-methyl-2-cyclohexen-1-ol 
• 58940-78-6 2-Chlor-3-oxo-6-methyl-cyclohexen 
• 58940-81-1 2,2,3-Trichlor-4-methyl-cyclohexanon 
• 58940-82-2 2,2,6-Trichlor-4-methyl-cyclohexanon 
• 7625-64-1 p-tolyl-carbamic acid benzyl ester 
• 27250-49-3 (3S,4S)-4-methyl-3-phenylcyclohexanone 
• 1373049-06-9 (3S,4S)-3-(4-methoxyphenyl)-4-methylcyclohexanone 

Relevant articles and documents

BENZIMIDAZOLE AND HYDROGENATED CARBAZOLE DERIVATIVES AS GPX4 INHIBITORS

This present disclosure relates to compounds with ferroptosis inducing activity, a method of treating a subject with cancer with the compounds, and combination treatments with a second therapeutic agent.

Bidentate Nitrogen-Ligated I(V) Reagents, Bi(N)-HVIs: Preparation, Stability, Structure, and Reactivity

Hypervalent iodine(V) reagents are a powerful class of organic oxidants. While the use of I(V) compounds Dess-Martin periodinane and IBX is widespread, this reagent class has long been plagued by issues of solubility and stability. Extensive effort has been made for derivatizing these scaffolds to modulate reactivity and physical properties but considerable room for innovation still exists. Herein, we describe the preparation, thermal stability, optimized geometries, and synthetic utility of an emerging class of I(V) reagents, Bi(N)-HVIs, possessing datively bound bidentate nitrogen ligands on the iodine center. Bi(N)-HVIs display favorable safety profiles, improved solubility, and comparable to superior oxidative reactivity relative to common I(V) reagents. The highly modular synthesis and in situ generation of Bi(N)-HVIs provides a novel and convenient screening platform for I(V) reagent and reaction development.

Palladium-Mediated Remote Functionalization in γ- And ?-Arylations and Alkenylations of Unblocked Cyclic Enones

We report herein an extensive investigation of simple and regioselective endo- as well as exo-γ-arylations of silyl-dienol ethers of unblocked cyclic enones with the utilization of palladium-catalyzed, modified Kuwajima-Urabe conditions. We have also successfully explored a new exo-?-arylation of silyl-trienol ethers of π-extended cyclic enones. In addition, we also report, herein, exclusive γ- and ?-alkenylation of silyl-dienol and silyl-trienol ethers of cyclic enones.