75345-82-3

Basic information

• Product Name: (C₆H₅CH₂)Co((HO)NC(CH₃)C(CH₃)N(O))2
• CAS NO: 75345-82-3
• Molecular Weight: 380.349
• Mol File: 75345-82-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (C₆H₅CH₂)Co((HO)NC(CH₃)C(CH₃)N(O))2(CAS DataBase Reference)
• NIST Chemistry Reference: (C₆H₅CH₂)Co((HO)NC(CH₃)C(CH₃)N(O))2(75345-82-3)
• EPA Substance Registry System: (C₆H₅CH₂)Co((HO)NC(CH₃)C(CH₃)N(O))2(75345-82-3)

Safety Data

• Hazardous Substances Data: 75345-82-3(Hazardous Substances Data)

Upstream product

• 103258-97-5 (1R,4S,8R,11S)-(1,4,8,11-tetramethyl-1,4,8,11-tetraazacyclotetradecane)(benzyl)nickel(II) 
• 3252-99-1 bis(dimethylglyoximato)cobalt(II) 

Relevant articles and documents

Kinetics and mechanism of iodination of para-substituted benzylbis(dimethylglyoximato)(pyridine)cobalt(III). High reactivity of the base-off form

A kinetic study of the iodination of p-XC6H4CH2Co(DH)2(py) (X = methoxy, methyl, H, chloro, nitro; DH = monoanion of dimethylglyoxime; py = pyridine) revealed the rate-determining dissociation of pyridine and subsequent rapid reaction of the base-free form with iodine. The high reactivity of the base-free form is discussed in relation to inner-sphere electron transfer. The rates of dissociation of pyridine showed a Hammett-like linear free-energy relationship with a ρ+ of -1.48.