75363-59-6Relevant articles and documents
Stereoselective Synthesis of Alcohols, XXII. E/Z-Selectivity on Addition of α-Substituted Allylboronates to Aldehydes
Hoffmann, Reinhard W.,Landmann, Bernd
, p. 1039 - 1053 (2007/10/02)
α-Heterosubstituted allylboronates 7 are prepared.Addition of 7 to aldehydes results in E/Z-isomeric homoallyl alcohols 13 and 14.The reasons for the predominant formation of the Z-isomer 14 are discussed.The Z-bromo olefins 16 and 20 obtained in this way serve as starting point for chain extension or formation of δ-lactones 21.
Partial syntheses of methyl dehydrojasmonate and tuberolactone
Dubs,Stussi
, p. 998 - 1003 (2007/10/11)
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